The oxidations of twenty five organic and inorganic species, with solublised manganese(IV), were found to elicit analytically useful chemiluminescence with detection limits (3 × S/N) for Mn(II), Fe(II), morphine and codeine of 5 × 10–8 M, 2.5 × 10–7 M, 7.5 × 10–8 M and 5 × 10–8 M, respectively. Additionally, the corrected spectra from four different analytes gave wavelengths of maximum emission in the range from 733 nm up to 740 nm suggesting that all these chemiluminescence reactions shared a common emitting species.
Field of Research
030199 Analytical Chemistry not elsewhere classified
Socio Economic Objective
970103 Expanding Knowledge in the Chemical Sciences
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