Soluble manganese (IV); a new chemiluminescence reagent
Barnett, Neil, Hindson, Benjamin, Lewis, Simon, Jones, Phillip and Worsfold, Paul 2001, Soluble manganese (IV); a new chemiluminescence reagent, Analyst, vol. 126, pp. 1636-1639.
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Soluble manganese (IV); a new chemiluminescence reagent
The oxidations of twenty five organic and inorganic species, with solublised manganese(IV), were found to elicit analytically useful chemiluminescence with detection limits (3 × S/N) for Mn(II), Fe(II), morphine and codeine of 5 × 10–8 M, 2.5 × 10–7 M, 7.5 × 10–8 M and 5 × 10–8 M, respectively. Additionally, the corrected spectra from four different analytes gave wavelengths of maximum emission in the range from 733 nm up to 740 nm suggesting that all these chemiluminescence reactions shared a common emitting species.
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eng
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030199 Analytical Chemistry not elsewhere classified