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Chiral trialkoxysilanols derived from terpene alcohols. Molecular structures of tris([(1S)-endo]-(-)-bornoxy)silanol and tetrakis((-)-menthoxy)silane

Beckmann, Jens, Dakternieks, Dainis and Tiekink, Edward R.T. 2002, Chiral trialkoxysilanols derived from terpene alcohols. Molecular structures of tris([(1S)-endo]-(-)-bornoxy)silanol and tetrakis((-)-menthoxy)silane, Journal of organometallic chemistry, vol. 648, no. 1-2, pp. 188-192, doi: 10.1016/S0022-328X(01)01420-6.

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Title Chiral trialkoxysilanols derived from terpene alcohols. Molecular structures of tris([(1S)-endo]-(-)-bornoxy)silanol and tetrakis((-)-menthoxy)silane
Formatted title Chiral trialkoxysilanols derived from terpene alcohols. Molecular structures of tris([(1S)-endo]-(-)-bornoxy)silanol and tetrakis((-)-menthoxy)silane
Author(s) Beckmann, Jens
Dakternieks, Dainis
Tiekink, Edward R.T.
Journal name Journal of organometallic chemistry
Volume number 648
Issue number 1-2
Start page 188
End page 192
Publisher Elsevier Science SA
Place of publication New York, N.Y.
Publication date 2002-04-01
ISSN 0022-328X
1872-8561
Keyword(s) trialkoxysilanols
chiral
terpenes
Summary Terpene alcohols (−)-menthol and [(1S)-endo]-(−)-borneol react with SiCl4 in the presence of base to give (MenO)3SiCl (1) and (BorO)3SiCl (2) in high yields. Hydrolysis of 1 yields (MenO)3SiOH (4) and (MenO)4Si (3). Hydrolysis of 2 yields only (BorO)3SiOH (5). The crystal structures of 3 and 5 are reported.


Language eng
DOI 10.1016/S0022-328X(01)01420-6
Field of Research 039904 Organometallic Chemistry
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2002, Elsevier Science B.V.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30001560

Document type: Journal Article
Collection: School of Biological and Chemical Sciences
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