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Extension ladders - synthesis and characterisation of new spacer-bridged tetraorganodistannoxanes

Dakternieks, Dainis, Duthie, Andrew, Jurkschat, Klaus, Schurmann, Markus and Tiekink, Edward R.T. 2002, Extension ladders - synthesis and characterisation of new spacer-bridged tetraorganodistannoxanes, Main group metal chemistry, vol. 25, no. 1, pp. 73-76.

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Title Extension ladders - synthesis and characterisation of new spacer-bridged tetraorganodistannoxanes
Author(s) Dakternieks, Dainis
Duthie, Andrew
Jurkschat, Klaus
Schurmann, Markus
Tiekink, Edward R.T.
Journal name Main group metal chemistry
Volume number 25
Issue number 1
Start page 73
End page 76
Publisher Freund Publishing House
Place of publication London, England
Publication date 2002
ISSN 0334-7575
0792-1241
Summary Preliminary results are described on the synthesis and characterization of novel spacer-bridged tetraorganodistannoxanes, {[[R(Cl)Sn]2(CH2)2]O}4 (n = 5 – 8, 10, 12; R = CH2SiMe3) containing particularly long organic spacers. In the solid state, these compounds reveal typical double-ladder structures with eight tin atoms per molecule, whereas in solution a partial and reversible rearrangement takes place to form tetraorganodistannoxanes, {[[R(Cl)Sn]2(CH2)n]O}2 (n = 5 – 8, 10, 12; R = CH2SiMe3), having four tin atoms per molecule.
Language eng
Field of Research 039904 Organometallic Chemistry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2002, Walter de Gruyter
Persistent URL http://hdl.handle.net/10536/DRO/DU:30001563

Document type: Journal Article
Collections: School of Biological and Chemical Sciences
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Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.