Synthesis and preliminary analytical evaluation of the chemiluminescence from (4-[4-(dichloromethylsilanyl)-butyl]-4`-methyl-2,2`-bipyridyl)bis(2,2`-bipyridyl)ruthenium(II) covalently bonded to silica particles

Barnett, Neil, Bos, Richard, Brand, Holger, Jones, Phillip, Lim, Kieran, Purcell, Stuart and Russell, Richard 2002, Synthesis and preliminary analytical evaluation of the chemiluminescence from (4-[4-(dichloromethylsilanyl)-butyl]-4`-methyl-2,2`-bipyridyl)bis(2,2`-bipyridyl)ruthenium(II) covalently bonded to silica particles, Analyst, vol. 127, no. 4, pp. 455-458.

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Title Synthesis and preliminary analytical evaluation of the chemiluminescence from (4-[4-(dichloromethylsilanyl)-butyl]-4`-methyl-2,2`-bipyridyl)bis(2,2`-bipyridyl)ruthenium(II) covalently bonded to silica particles
Author(s) Barnett, Neil
Bos, Richard
Brand, Holger
Jones, Phillip
Lim, Kieran
Purcell, Stuart
Russell, Richard
Journal name Analyst
Volume number 127
Issue number 4
Start page 455
End page 458
Publisher Royal Society of Chemistry
Place of publication London, England
Publication date 2002
ISSN 0003-2654
1364-5528
Summary This paper describes, for the first time, a simple and effective synthetic route for covalently bonding the chemiluminescence reagent, (4-[4-(dichloromethylsilanyl)-butyl]-4’-methyl-2,2’-bipyridyl)bis(2,2’-bipyridyl)ruthenium(II) onto silica particles. The subsequent preparation of chemically regeneratable detection cells and their preliminary analytical evaluation with both sequential injection analysis and flow injection analysis are also reported. Unoptimised analytical figures of merit were established for standard solutions of codeine and sodium oxalate with detection limits calculated from three times the standard deviation of the blank signal, of 1 × 10–8 M and 3 × 10–7 M respectively. The chemically immobilised reagent exhibited some intriguing solvent and kinetic effects, which are also briefly discussed.
Language eng
Field of Research 030103 Flow Analysis
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2002, Royal Society of Chemistry
Persistent URL http://hdl.handle.net/10536/DRO/DU:30001693

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