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Studies on the mechanism of the peroxyoxalate chemiluminescence reaction Part 1. Confirmation of 1,2-dioxetanedione as an intermediate using 13C nuclear magnetic resonance spectroscopy

Bos, Richard, Barnett, Neil, Dyson, Gail, Lim, Kieran, Russell, Richard and Watson, Simon 2004, Studies on the mechanism of the peroxyoxalate chemiluminescence reaction Part 1. Confirmation of 1,2-dioxetanedione as an intermediate using 13C nuclear magnetic resonance spectroscopy, Analytica chimica acta, vol. 502, no. 2, pp. 141-147.

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Title Studies on the mechanism of the peroxyoxalate chemiluminescence reaction Part 1. Confirmation of 1,2-dioxetanedione as an intermediate using 13C nuclear magnetic resonance spectroscopy
Formatted title Studies on the mechanism of the peroxyoxalate chemiluminescence reaction Part 1. Confirmation of 1,2-dioxetanedione as an intermediate using 13C nuclear magnetic resonance spectroscopy
Author(s) Bos, Richard
Barnett, Neil
Dyson, Gail
Lim, Kieran
Russell, Richard
Watson, Simon
Journal name Analytica chimica acta
Volume number 502
Issue number 2
Start page 141
End page 147
Publisher Elsevier
Place of publication Amsterdam, Netherlands
Publication date 2004-01-30
ISSN 0003-2670
1873-4324
Keyword(s) peroxyoxalate chemiluminescence intermediate
1,2-Dioxetanedione
nuclear magnetic resonance spectroscopy
ab initio quantum calculations
Summary A simple model peroxyoxalate chemiluminescence system was monitored directly across a range of temperatures (from −80 to +20 °C) using 13C nuclear magnetic resonance spectroscopy. These experiments were made possible by the utilisation of 13C doubly labelled oxalyl chloride, which was reacted with anhydrous hydrogen peroxide in dry tetrahydrofuran. Ab initio quantum calculations were also performed to estimate the 13C nuclear magnetic resonance (NMR) shift of the most commonly postulated key intermediate 1,2-dioxetanedione and this data, in concert with the spectroscopic evidence, confirmed its presence during the reaction.
Language eng
Field of Research 030606 Structural Chemistry and Spectroscopy
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2004, Elsevier
Persistent URL http://hdl.handle.net/10536/DRO/DU:30002353

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Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.