The emitting species formed by the oxidation of hydrazides with hypohalites or N-halosuccinimides

Francis, Paul 2004, The emitting species formed by the oxidation of hydrazides with hypohalites or N-halosuccinimides, Luminescence, vol. 19, no. 4, pp. 205-208.

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Title The emitting species formed by the oxidation of hydrazides with hypohalites or N-halosuccinimides
Author(s) Francis, Paul
Journal name Luminescence
Volume number 19
Issue number 4
Start page 205
End page 208
Publisher John Wiley and Sons
Place of publication Bognor Regis, England
Publication date 2004-07
ISSN 1522-7235
1522-7243
Keyword(s) emitting species
chemiluminescence spectra
reaction mechanism
hydrazides
hypochlorite
N-bromosuccinimide
Summary The chemiluminescence accompanying the oxidation of salicylic hydrazide (2-hydroxybenzoic acid hydrazide) with hypochlorite, hypobromite, N-chlorosuccinimide, N-bromosuccinimide or hydrogen peroxide with cobalt(II) matched the photoluminescence emission of salicylic acid. In a related reaction, the oxidation of a mixture of isoniazid and ammonia, a synergistic effect was observed. The chemiluminescence spectrum for this reaction matches that accompanying the oxidation of the hydrazide, rather than the oxidation of ammonia. These results were used to assess mechanisms proposed by previous authors.
Language eng
Field of Research 030101 Analytical Spectrometry
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2004, John Wiley & Sons
Persistent URL http://hdl.handle.net/10536/DRO/DU:30002787

Document type: Journal Article
Collection: School of Biological and Chemical Sciences
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