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Effect of oxidant type on the chemiluminescence intensity from the reaction of tris(2,2’-biyridyl)ruthenium(III) with various organic acids

Gorman, Bree, Lim, Kieran, Hogan, Conor and Barnett, Neil 2007, Effect of oxidant type on the chemiluminescence intensity from the reaction of tris(2,2’-biyridyl)ruthenium(III) with various organic acids, Talanta, vol. 72, no. 2, pp. 568-574.

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Title Effect of oxidant type on the chemiluminescence intensity from the reaction of tris(2,2’-biyridyl)ruthenium(III) with various organic acids
Author(s) Gorman, Bree
Lim, Kieran
Hogan, Conor
Barnett, Neil
Journal name Talanta
Volume number 72
Issue number 2
Start page 568
End page 574
Publisher Elsevier BV
Place of publication Amsterdam, Netherlands
Publication date 2007-04-30
ISSN 0039-9140
1873-3573
Keyword(s) tris(2,2′-bipyridyl)ruthenium(II) chemiluminescence
organic acids
Ce(IV)
electrochemiluminescence
Summary An investigation into the chemiluminescence of fourteen organic acids and tris(2,2′-bipyridyl)ruthenium(II) was undertaken. Particular emphasis was placed upon the method of production of the reagent, tris(2,2′-bipyridyl)ruthenium(III), with cerium(IV) sulfate, potassium permanganate, lead dioxide and electrochemical generation. Analytically useful chemiluminescence was observed when Ce(IV) or potassium permanganate were employed as oxidants. The kinetics of analyte oxidation was related to the intensity of the chemiluminescence emission, which increased by three orders of magnitude for tartaric acid after 40 h of oxidation.
Notes Available online 27 December 2006.
Language eng
Field of Research 030101 Analytical Spectrometry
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2006 Elsevier B.V.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30007608

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