Effect of oxidant type on the chemiluminescence intensity from the reaction of tris(2,2’-biyridyl)ruthenium(III) with various organic acids
Gorman, Bree, Lim, Kieran, Hogan, Conor and Barnett, Neil 2007, Effect of oxidant type on the chemiluminescence intensity from the reaction of tris(2,2’-biyridyl)ruthenium(III) with various organic acids, Talanta, vol. 72, no. 2, pp. 568-574.
(Some files may be inaccessible until you login with your Deakin Research Online credentials)
An investigation into the chemiluminescence of fourteen organic acids and tris(2,2′-bipyridyl)ruthenium(II) was undertaken. Particular emphasis was placed upon the method of production of the reagent, tris(2,2′-bipyridyl)ruthenium(III), with cerium(IV) sulfate, potassium permanganate, lead dioxide and electrochemical generation. Analytically useful chemiluminescence was observed when Ce(IV) or potassium permanganate were employed as oxidants. The kinetics of analyte oxidation was related to the intensity of the chemiluminescence emission, which increased by three orders of magnitude for tartaric acid after 40 h of oxidation.
Unless expressly stated otherwise, the copyright for items in Deakin Research Online is owned by the author, with all rights reserved.
Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO.
If you believe that your rights have been infringed by this repository, please contact firstname.lastname@example.org.