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Synthesis and polymerization studies of 3-(+) and (-) -menthyl carboxylate pyrroles

Foitzik, Richard, Bowen, Elspeth, Taylor, Amelia, Pfeffer, Frederick and Kaynak, Akif 2007, Synthesis and polymerization studies of 3-(+) and (-) -menthyl carboxylate pyrroles, Synthetic metals, vol. 157, no. 22-23, pp. 924-929.

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Title Synthesis and polymerization studies of 3-(+) and (-) -menthyl carboxylate pyrroles
Author(s) Foitzik, Richard
Bowen, Elspeth
Taylor, Amelia
Pfeffer, Frederick
Kaynak, Akif
Journal name Synthetic metals
Volume number 157
Issue number 22-23
Start page 924
End page 929
Publisher Elsevier SA
Place of publication Lausanne, Switzerland
Publication date 2007-11
ISSN 0379-6779
Keyword(s) conductive polymers
chiral polymers
wool
coloured polymers
chemical polymerization
Summary The synthesis of 3-(−)- and 3-(+)-menthyl carboxylate pyrrole was achieved in four high yielding steps, including the triisopropylsilyl (TIPS) protection of the pyrrole nitrogen, bromination of the 3-position, lithium halogen exchange followed by reaction with menthyl chloroformate, and finally de-protection. Chemical polymerization of both the TIPS protected, and non-protected, menthyl carboxylate pyrroles was performed and the resulting polymers exhibited conductivity ranging from 0.6 to 2.3 S/cm. Polymerization of the 3-menthyl-N-TIPS pyrrole on the surface of wool was achieved by using solution and mist polymerization methods.
Language eng
Field of Research 091209 Polymers and Plastics
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2007, Elsevier B.V.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30007636

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