Manganese dioxide allylic and benzylic oxidation reactions in ionic liquids

Hemeon, Ivan, Barnett, Neil, Gathergood, Nicholas, Scammells, Peter and Singer, Robert 2004, Manganese dioxide allylic and benzylic oxidation reactions in ionic liquids, Australian journal of chemistry, vol. 57, pp. 125-128.

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Title Manganese dioxide allylic and benzylic oxidation reactions in ionic liquids
Author(s) Hemeon, Ivan
Barnett, Neil
Gathergood, Nicholas
Scammells, Peter
Singer, Robert
Journal name Australian journal of chemistry
Volume number 57
Start page 125
End page 128
Publisher CSIRO Publishing
Place of publication Melbourne, Vic.
Publication date 2004
ISSN 0004-9425
1445-0038
Keyword(s) ionic liquids
Mn
oxidation
solvent effects
Summary Ionic liquids 1-butyl-3-methylimidazolium tetrafluoroborate [bmIm][BF4] and 1-butyl-3-methylimidazolium hexafluorophosphate [bmIm][PF6] were evaluated as reaction media for allylic and benzylic oxidation reactions using manganese dioxide. The use of ionic liquids as an extractant in the reaction work-up was also investigated. Procedures for recycling of the [bmIm][PF6] ionic liquids used in these MnO2 oxidation reactions were also developed.
Notes Available online 27 December 2006
Language eng
Field of Research 030503 Organic Chemical Synthesis
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2004, CSIRO
Persistent URL http://hdl.handle.net/10536/DRO/DU:30008736

Document type: Journal Article
Collection: School of Biological and Chemical Sciences
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