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The interplay of secondary Te···N, Te···O, Te···I and I···I interactions, Te···π contacts and π-stacking in the supramolecular structures of [{2-(4-nitrobenzylideneamino)-5-methyl}phenyl](4-methoxyphenyl)tellurium dihalides

Chauhan, Ashok, Anamika,, Kumar, Arun, Srivastava, Ramesh, Butcher, Ray, Beckmann, Jens and Duthie, Andrew 2005, The interplay of secondary Te···N, Te···O, Te···I and I···I interactions, Te···π contacts and π-stacking in the supramolecular structures of [{2-(4-nitrobenzylideneamino)-5-methyl}phenyl](4-methoxyphenyl)tellurium dihalides, Journal of organometallic chemistry, vol. 690, no. 5, pp. 1350-1355, doi: 10.1016/j.jorganchem.2004.12.001.

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Title The interplay of secondary Te···N, Te···O, Te···I and I···I interactions, Te···π contacts and π-stacking in the supramolecular structures of [{2-(4-nitrobenzylideneamino)-5-methyl}phenyl](4-methoxyphenyl)tellurium dihalides
Formatted title Interplay of secondary Te···N, Te···O, Te···I and I···I interactions, Te···π contacts and π-stacking in the supramolecular structures of [{2-(4-nitrobenzylideneamino)-5-methyl}phenyl](4-methoxyphenyl)tellurium dihalides
Author(s) Chauhan, Ashok
Anamika,
Kumar, Arun
Srivastava, Ramesh
Butcher, Ray
Beckmann, Jens
Duthie, Andrew
Journal name Journal of organometallic chemistry
Volume number 690
Issue number 5
Start page 1350
End page 1355
Publisher Elsevier B.V.
Place of publication Amsterdam, The Netherlands
Publication date 2005-03-01
ISSN 0022-328X
1872-8561
Keyword(s) intramolecular coordination
secondary interactions
diorganotellurium dihalides
Summary The unsymmetrical1y substituted diorganotellurium dihalides [2-(4,4'-N02C6H4CHNC6H3Me]RTeX2 (R = 4-MeOC6H4, X = Cl,
1a; Br, 1b; I, 1c; R =4-MeC6H4 ; X = Cl, 2; R =C6H5, X = Cl, 3) were prepared in good yields and characterized by solution and solid-state 125Te NMR spectroscopy, IR spectroscopy and X-ray crystallography. In the solid-state, molecular structures of 1a and 1c possess scarcely observed 1,4-type intramolecular Te···N secondary interaction. Crystal packing of these compounds show an unusually rich diversity of intermolecular secondary, Te·· ·0, Te· .. \ and 1···1 interactions, Te·· ·π contacts as well as extensive
π-stacking of the organic substituents.
Language eng
DOI 10.1016/j.jorganchem.2004.12.001
Field of Research 039904 Organometallic Chemistry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2004, Elsevier B.V.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30008930

Document type: Journal Article
Collection: School of Biological and Chemical Sciences
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