Luminescence and microstructure of Sr2Mg(BO3)2 doped with Eu

Lin, Cao, Liu, Xingren, Jing, X., Liu, Ying and Chen, Ying 2005, Luminescence and microstructure of Sr2Mg(BO3)2 doped with Eu, Journal of rare earths, vol. 23, no. Suppl. 3, pp. 48-50.

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Title Luminescence and microstructure of Sr2Mg(BO3)2 doped with Eu
Formatted title Luminescence and microstructure of Eu doped Sr2Mg(BO3)2
Author(s) Lin, Cao
Liu, Xingren
Jing, X.
Liu, Ying
Chen, Ying
Journal name Journal of rare earths
Volume number 23
Issue number Suppl. 3
Start page 48
End page 50
Total pages 3 pp
Publisher Elsevier BV
Place of publication Amsterdam, The Netherlands
Publication date 2005-12
ISSN 1002-0721
1000-4343
Keyword(s) luminescence
borate
microstructure
rare earths
Summary Sr2Mg(B03)2 doped with Eu was synthesized respectively in air and weak reducing atmosphere (combustion of carbon particle), whose photoluminescence characteristics and structure were also studied at room-temperature. In air, the fluorescent body's color was white for different synthesized temperatures. At room temperature, the sample was excited and showed red typical emission spectrum of Eu3+ whose emission apex were sharp near 612 nm and emission spect~m was made up of the charge transformation band (CTB) of Eu3 + and excitation spectrum of 4f→4f high energy level transition, then reached the area of VUV. However, under reducing atmosphere (combustion of carbon particles), the color of the sample yielded was yellow, whose color became deeper with increasing temperature and showed phase transition. Using UV excitation, the luminescence of yellow sample was very weak. In a complicated broad spectrum at visible light area, the red emission spectrum of Eu2+ was not observed. Crystal structure and luminescence of the sample were completely different from the results of Diaz and Keszler. Two samples were prepared under oxidation and reducing atmosphere at high temperature, which were different on crystal structure and microstructure. By studying Sr2Mg(B03)2:Eu3+ a series of directional faults or educts were found, because Eu3 + ions substituted for Sr2 + ions. However, microstructure of Sr2Mg(B03 )2: Eu2 + is more complicated, whose excitation spectrum might be excited by Eu2 +. By XRD patten of the samples, phase transitibn could be found. Twins and clusters that were formed from point defect such as interstitial atom and big angle crystal boundary could be found by TEM.
Language eng
Field of Research 100706 Nanofabrication, Growth and Self Assembly
100708 Nanomaterials
Socio Economic Objective 970110 Expanding Knowledge in Technology
HERDC Research category C1.1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Persistent URL http://hdl.handle.net/10536/DRO/DU:30016475

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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