Size matters—strong binding of the terephthalate dianion by thiourea functionalised fused [n]polynorbornane hosts
Lowe, Adam J. and Pfeffer, Frederick M. 2008, Size matters—strong binding of the terephthalate dianion by thiourea functionalised fused [n]polynorbornane hosts, Chemical communications, no. 16, pp. 1871-1873.
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Title
Size matters—strong binding of the terephthalate dianion by thiourea functionalised fused [n]polynorbornane hosts
Remarkably strong binding of the new [5]polynorbornane based host 2b to the terephthalate dianion is based on size complementarity of the preorganised binding cleft with the rigid dicarboxylate guest.
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eng
Field of Research
030503 Organic Chemical Synthesis
Socio Economic Objective
970103 Expanding Knowledge in the Chemical Sciences