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Factors influencing anion binding stoichiometry : the subtle influence of electronic effects

Lowe, Adam J., Dyson, Gail A. and Pfeffer, Frederick M. 2008, Factors influencing anion binding stoichiometry : the subtle influence of electronic effects, European journal of organic chemistry, vol. 2008, no. 9, pp. 1559-1567.

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Title Factors influencing anion binding stoichiometry : the subtle influence of electronic effects
Author(s) Lowe, Adam J.
Dyson, Gail A.
Pfeffer, Frederick M.
Journal name European journal of organic chemistry
Volume number 2008
Issue number 9
Start page 1559
End page 1567
Publisher Wiley - V C H Verlag GmbH & Co. KGaA
Place of publication Germany
Publication date 2008
ISSN 1434-193X
Keyword(s) Anion recognition
Preorganisation
Norbornene
Supramolecular chemistry
Hydrogen bonding
Summary Six new, charge-neutral norbornene-based receptors 1a,1b– 3a,3b were prepared, and their ability to interact with simple anions in DMSO was investigated using 1H NMR and UV/ Vis spectroscopy. Binding of dihydrogenphosphate by the six receptors appeared to be based solely on steric constraints. In contrast, the binding stoichiometry of 3a and 3b to acetate was controlled by subtle electronic factors.
Language eng
Field of Research 030503 Organic Chemical Synthesis
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2008, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Persistent URL http://hdl.handle.net/10536/DRO/DU:30017614

Document type: Journal Article
Collection: School of Life and Environmental Sciences
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Created: Fri, 14 Aug 2009, 13:55:15 EST