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Manganese (III) and manganese (IV) as chemiluminescence reagents : a review

Brown, Allyson J., Francis, Paul S., Adcock, Jacqui L., Lim, Kieran F. and Barnett, Neil W. 2008, Manganese (III) and manganese (IV) as chemiluminescence reagents : a review, Analytica chimica acta, vol. 624, no. 2, pp. 175-183.

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Title Manganese (III) and manganese (IV) as chemiluminescence reagents : a review
Author(s) Brown, Allyson J.
Francis, Paul S.
Adcock, Jacqui L.
Lim, Kieran F.
Barnett, Neil W.
Journal name Analytica chimica acta
Volume number 624
Issue number 2
Start page 175
End page 183
Publisher Elsevier B. V.
Place of publication Amsterdam, The Netherlands
Publication date 2008-08-29
ISSN 0003-2670
1873-4324
0924-2031
Keyword(s) chemiluminescence
manganese(III)
manganese(IV)
manganese dioxide
flow injection analysis
high-performance liquid chromatography
Summary Although potassium permanganate [Mn(VII)] has been used extensively as a chemiluminescence reagent for many decades, other manganese-based oxidants have only recently been explored for this purpose. There is strong evidence to suggest that, like permanganate, manganese(III) and manganese(IV) oxidants react with many molecules to produce an excited manganese(II) species that emits light. However, these reagents differ markedly in terms of selectivity, and possess characteristics that provide new avenues for detection, such as the immobilisation of solid manganese dioxide, the production of ‘soluble’ manganese(IV) nanoparticles, and the electrochemical generation of manganese(III). In this review we examine the emergence of these alternative manganese oxidants as chemiluminescence reagents.
Language eng
Field of Research 030103 Flow Analysis
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
HERDC collection year 2008
Copyright notice ©2008, Elsevier B.V.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30017638

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