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Emitting species in chemiluminescence reactions with acidic potassium permanganate : a re-evaluation based on new spectroscopic evidence

Adcock, Jacqui L., Francis, Paul S. and Barnett, Neil W. 2009, Emitting species in chemiluminescence reactions with acidic potassium permanganate : a re-evaluation based on new spectroscopic evidence, Journal of fluorescence, vol. 19, no. 5, pp. 867-874.

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Title Emitting species in chemiluminescence reactions with acidic potassium permanganate : a re-evaluation based on new spectroscopic evidence
Author(s) Adcock, Jacqui L.
Francis, Paul S.
Barnett, Neil W.
Journal name Journal of fluorescence
Volume number 19
Issue number 5
Start page 867
End page 874
Total pages 8
Publisher Springer New York LLC
Place of publication New York, N.Y.
Publication date 2009-09
ISSN 1053-0509
1573-4994
Keyword(s) chemiluminescence spectra
fluorescence spectra
emitting species
energy transfer
potassium permanganate
Summary The reaction of acidic potassium permanganate with a wide range of compounds is known to produce a broad red emission, and there is strong evidence for an excited manganese(II) emitting species. Nevertheless, numerous researchers have proposed other emitters for reactions with acidic potassium permanganate, particularly for systems where fluorescent compounds were present, either as enhancers or reaction products. We have examined many reactions of this type and found that, in most cases, the same red emission was produced. There were, however, some exceptions, including the oxidation of dihydralazine, certain thiols and sulphite (each in the presence of an enhancer).
Notes Published online: 8 April 2009
Language eng
Field of Research 030199 Analytical Chemistry not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
HERDC collection year 2009
Copyright notice ©2009, Springer Science + Business Media, LLC
Persistent URL http://hdl.handle.net/10536/DRO/DU:30029376

Document type: Journal Article
Collection: School of Life and Environmental Sciences
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