Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors

Adebahr, J., Forsyth, M. and MacFarlane, D. R. 2005, Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors, Electrochimica acta, vol. 50, no. 19, pp. 3853-3858.

Attached Files
Name Description MIMEType Size Downloads

Title Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors
Author(s) Adebahr, J.
Forsyth, M.
MacFarlane, D. R.
Journal name Electrochimica acta
Volume number 50
Issue number 19
Start page 3853
End page 3858
Publisher Elsevier Science Pub. Co.
Place of publication New York, N.Y
Publication date 2005-06-30
ISSN 0013-4686
1873-3859
Keyword(s) pyrrolidinium based salts
NMR and Raman spectroscopy
plastic crystals
Summary Dimethyl-pyrrolidinum-based salts have been investigated by means of DSC, conductivity, NMR and Raman spectroscopy. The investigation aims to study the effect of the anion on the behaviour of the salt, in terms of plastic properties as well as rotational degrees of freedom of the cation. The materials range from the non-plastic iodide salt to the highly plastic BF4 salt, which flows under its own weight at elevated temperatures. The different rotational and translational motions of the cations, and the difference between rotator and plastic phases are discussed.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2005, Elsevier Ltd.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030045

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
Connect to link resolver
 
Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved.

Versions
Version Filter Type
Citation counts: TR Web of Science Citation Count  Cited 17 times in TR Web of Science
Scopus Citation Count Cited 18 times in Scopus
Google Scholar Search Google Scholar
Access Statistics: 315 Abstract Views, 0 File Downloads  -  Detailed Statistics
Created: Fri, 10 Sep 2010, 15:07:31 EST

Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.