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Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors Adebahr, J., Forsyth, M. and MacFarlane, D. R. 2005, Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors, Electrochimica acta, vol. 50, no. 19, pp. 3853-3858. Attached Files Name Description MIMEType Size Downloads Title Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors Author(s) Adebahr, J. Forsyth, M. MacFarlane, D. R. Journal name Electrochimica acta Volume number 50 Issue number 19 Start page 3853 End page 3858 Publisher Elsevier Science Pub. Co. Place of publication New York, N.Y Publication date 2005-06-30 ISSN 0013-4686 1873-3859 Keyword(s) pyrrolidinium based salts NMR and Raman spectroscopy plastic crystals Summary Dimethyl-pyrrolidinum-based salts have been investigated by means of DSC, conductivity, NMR and Raman spectroscopy. The investigation aims to study the effect of the anion on the behaviour of the salt, in terms of plastic properties as well as rotational degrees of freedom of the cation. The materials range from the non-plastic iodide salt to the highly plastic BF4 salt, which flows under its own weight at elevated temperatures. The different rotational and translational motions of the cations, and the difference between rotator and plastic phases are discussed. Language eng Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2005, Elsevier Ltd. Persistent URL http://hdl.handle.net/10536/DRO/DU:30030045 Document type: Journal Article Collection: Institute for Technology Research and Innovation Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 10 Sep 2010, 15:07:32 EST Tue, 21 Sep 2010, 11:35:04 EST Tue, 21 Sep 2010, 11:36:19 EST Filtered Full Citation counts:   Cited 17 times in TR Web of Science Cited 19 times in Scopus Search Google Scholar Access Statistics: 333 Abstract Views, 0 File Downloads  -  Detailed Statistics Created: Fri, 10 Sep 2010, 15:07:31 EST

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