Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors

Adebahr, J., Forsyth, M. and MacFarlane, D. R. 2005, Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors, Electrochimica acta, vol. 50, no. 19, pp. 3853-3858, doi: 10.1016/j.electacta.2005.02.064.

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Title Cation dynamics in dimethyl-pyrrolidinium-based solid-state ion conductors
Author(s) Adebahr, J.
Forsyth, M.ORCID iD for Forsyth, M.
MacFarlane, D. R.
Journal name Electrochimica acta
Volume number 50
Issue number 19
Start page 3853
End page 3858
Publisher Elsevier Science Pub. Co.
Place of publication New York, N.Y
Publication date 2005-06-30
ISSN 0013-4686
Keyword(s) pyrrolidinium based salts
NMR and Raman spectroscopy
plastic crystals
Summary Dimethyl-pyrrolidinum-based salts have been investigated by means of DSC, conductivity, NMR and Raman spectroscopy. The investigation aims to study the effect of the anion on the behaviour of the salt, in terms of plastic properties as well as rotational degrees of freedom of the cation. The materials range from the non-plastic iodide salt to the highly plastic BF4 salt, which flows under its own weight at elevated temperatures. The different rotational and translational motions of the cations, and the difference between rotator and plastic phases are discussed.
Language eng
DOI 10.1016/j.electacta.2005.02.064
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2005, Elsevier Ltd.
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