Exploring corrosion protection of Mg via ionic liquid pretreatment Birbilis, Nick, Howlett, Patrick C., MacFarlane, Douglas R. and Forsyth, Maria 2007, Exploring corrosion protection of Mg via ionic liquid pretreatment, Surface and coatings technology, vol. 201, no. 8, pp. 4496-4504, doi: 10.1016/j.surfcoat.2006.09.050. Attached Files Name Description MIMEType Size Downloads Title Exploring corrosion protection of Mg via ionic liquid pretreatment Author(s) Birbilis, Nick Howlett, Patrick C. orcid.org/0000-0002-2151-2932 MacFarlane, Douglas R. Forsyth, Maria orcid.org/0000-0002-4273-8105 Journal name Surface and coatings technology Volume number 201 Issue number 8 Start page 4496 End page 4504 Publisher Elsevier Science SA Place of publication Amsterdam, The Netherlands Publication date 2007-01-15 ISSN 0257-8972 Keyword(s) magnesium corrosion ionic liquid inhibition droplet-cell coating Summary We present the development of a 10–100 nanometer thick surface film upon pure Mg on exposure to an ionic liquid (IL) based on the bis(trifluoromethanesulfonyl)amide (TFSA) anion. This film formation is the result of the oxidative reactivity of the metal in the IL, with the subsequent effect of ultimately protecting the underlying metal from corrosion in aqueous chloride containing solution. Film formation was studied in the IL using an electrochemical droplet cell. It was seen that this film is adherent and subsequently facilitates appreciable protection against corrosion as judged by subsequent electrochemical testing in the form of potentiodynamic polarization and impedance spectroscopy, along with direct observation. The physical film morphology was studied by electron microscopy and focused ion beam. Language eng DOI 10.1016/j.surfcoat.2006.09.050 Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2006, Elsevier B.V. Persistent URL http://hdl.handle.net/10536/DRO/DU:30030069 Document type: Journal Article Collection: Institute for Technology Research and Innovation Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 10 Sep 2010, 15:07:55 EST Tue, 12 Oct 2010, 08:50:03 EST Tue, 12 Oct 2010, 08:51:44 EST Thu, 14 Oct 2010, 08:49:59 EST Thu, 09 Jan 2014, 10:37:32 EST Filtered Full Citation counts:   Cited 61 times in TR Web of Science Cited 75 times in Scopus Search Google Scholar Access Statistics: 547 Abstract Views, 0 File Downloads  -  Detailed Statistics Created: Fri, 10 Sep 2010, 15:07:55 EST

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