Crystal structure of a ceIII/feIII heterobimetallic complex
Deacon, Glen B., Forsyth, Craig M. and Forsyth, Maria 2003, Crystal structure of a ceIII/feIII heterobimetallic complex, Zeitschrift für anorganische und allgemeine chemie, vol. 629, no. 9, pp. 1472-1474, doi: 10.1002/zaac.200300089.
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Crystal structure of a ceIII/feIII heterobimetallic complex
A central μ3—O moiety linking two FeIII and one CeIII sites supported by two distinct heterometallic carboxylate bridging modes features in self-assembled [CeFe2(bpy)2(μ3—O)(μ—L)2(μ—LH)2(LH)(H2O)2]·0.5(bpy)·7H2O (1) (LH2 = glycolic acid), and the structure models potential bonding modes of the Rare Earth corrosion inhibitor Ce(glycolate)3 to iron or iron oxide.
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