Structural characterization of novel ionic salts incorporating trihalide anions

Dean, Pamela M., Clare, Bronya R., Armel, Vanessa, Pringle, Jennifer M., Forsyth, Craig M., Forsyth, Maria and MacFarlane, Douglas R. 2009, Structural characterization of novel ionic salts incorporating trihalide anions, Australian journal of chemistry, vol. 62, no. 4, pp. 334-340, doi: 10.1071/CH08456.

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Title Structural characterization of novel ionic salts incorporating trihalide anions
Author(s) Dean, Pamela M.
Clare, Bronya R.
Armel, Vanessa
Pringle, Jennifer M.ORCID iD for Pringle, Jennifer M.
Forsyth, Craig M.
Forsyth, MariaORCID iD for Forsyth, Maria
MacFarlane, Douglas R.
Journal name Australian journal of chemistry
Volume number 62
Issue number 4
Start page 334
End page 340
Total pages 7
Publisher CSIRO
Place of publication Melbourne, Vic.
Publication date 2009
ISSN 0004-9425
Summary The crystal structures of several low-melting salts containing trihalide ions, namely 1-ethyl-3-methylimidazolium tribromide ([C2mim][Br3]), 1-ethyl-1-methylpyrrolidinium tribromide ([C2mpyr][Br3]), and 1-propyl-1-methylpyrrolidinium triiodide ([C3mpyr][I3]), are reported for the first time. Thermal analysis reveals that the tribromide salts are lower-melting than their monohalide analogues. Analysis of the crystal structures allows examination of the influence of the anions on the physical properties of the salts.
Language eng
DOI 10.1071/CH08456
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2009, CSIRO
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