A study of hydrogen bonding in concentrated diol/water solutions by proton NMR correlations with glass formation Forsyth, Maria and MacFarlane, Douglas R. 1990, A study of hydrogen bonding in concentrated diol/water solutions by proton NMR correlations with glass formation, Journal of physical chemistry B : condensed matter, materials, surfaces, interfaces and biophysical, vol. 94, no. 17, pp. 6889-6893, doi: 10.1021/j100380a064. Attached Files Name Description MIMEType Size Downloads Title A study of hydrogen bonding in concentrated diol/water solutions by proton NMR correlations with glass formation Author(s) Forsyth, Maria orcid.org/0000-0002-4273-8105 MacFarlane, Douglas R. Journal name Journal of physical chemistry B : condensed matter, materials, surfaces, interfaces and biophysical Volume number 94 Issue number 17 Start page 6889 End page 6893 Publisher American Chemical Society Place of publication Washington, D.C. Publication date 1990-08 ISSN 1520-6106 1520-5207 Summary Solute/water interactions in a series of diol solutions have been investigated by 1H NMR. Strong hydrogen bonding between water and alcohols that are more basic than water is thought to result in lower chemical shifts of water protons compared to the case of pure water. This is attributed to a greater degree of covalent character in the hydrogen bonding between water and the more basic diols. The inductive effect of the methyl group and longer chain alkyls is observed to increase basicity in ethylene glycol, propylene glycol, and 2,3-butanediol solutions. A correlation between the glass-forming ability of the diol solutions and the stronger hydrogen-bonding solutes (i.e., stronger bases) is developed, with 2,3-butanediol best promoting glass formation at the lowest concentrations. Language eng DOI 10.1021/j100380a064 Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©1990, American Chemical Society Persistent URL http://hdl.handle.net/10536/DRO/DU:30030129 Document type: Journal Article Collection: Institute for Technology Research and Innovation Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 10 Sep 2010, 15:08:57 EST Thu, 23 Sep 2010, 14:16:47 EST Thu, 23 Sep 2010, 14:18:18 EST Mon, 16 Jun 2014, 16:23:07 EST Sat, 17 Jun 2017, 03:03:22 EST Filtered Full Citation counts:   Cited 11 times in TR Web of Science Cited 12 times in Scopus Search Google Scholar Access Statistics: 550 Abstract Views, 0 File Downloads  -  Detailed Statistics Created: Fri, 10 Sep 2010, 15:08:57 EST

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