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N-methyl-N-alkylpyrrolidinium nonafluoro-1-butanesulfonate salts : Ionic liquid properties and plastic crystal behaviour

Forsyth, Stewart A., Fraser, Kevin J., Howlett, Patrick C., MacFarlane, Douglas R. and Forsyth, Maria 2006, N-methyl-N-alkylpyrrolidinium nonafluoro-1-butanesulfonate salts : Ionic liquid properties and plastic crystal behaviour, Green chemistry, vol. 8, no. 3, pp. 256-261.

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Title N-methyl-N-alkylpyrrolidinium nonafluoro-1-butanesulfonate salts : Ionic liquid properties and plastic crystal behaviour
Formatted title N-methyl-N-alkylpyrrolidinium nonafluoro-1-butanesulfonate salts : Ionic liquid properties and plastic crystal behaviour
Author(s) Forsyth, Stewart A.
Fraser, Kevin J.
Howlett, Patrick C.
MacFarlane, Douglas R.
Forsyth, Maria
Journal name Green chemistry
Volume number 8
Issue number 3
Start page 256
End page 261
Publisher Royal Society of Chemistry
Place of publication London, England
Publication date 2006
ISSN 1463-9262
1463-9270
Summary A series of N-methyl-N-alkylpyrrolidinium nonafluoro-1-butanesulfonate salts were synthesised and characterised. The thermophysical characteristics of this family of salts have been investigated with respect to potential use as ionic liquids and solid electrolytes. N-Methyl-N-butylpyrrolidinium nonafluoro-1-butanesulfonate (p1,4NfO) has the lowest melting point of the family, at 94 °C. Electrochemical analysis of p1,4 NfO in the liquid state shows an electrochemical window of ~6 V. All compounds exhibit one or more solid–solid transitions at sub-ambient temperatures, indicating the existence of plastic crystal phases.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2006, The Royal Society of Chemistry
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030153

Document type: Journal Article
Collections: Institute for Technology Research and Innovation
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Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.