Methanesulfonate and p-toluenesulfonate salts of the N-methyl-N-alkylpyrrolidinium and quaternary ammonium cations : novel low cost ionic liquids Golding, J., Forsyth, S., MacFarlane, D. R., Forsyth, M. and Deacon, G. B. 2002, Methanesulfonate and p-toluenesulfonate salts of the N-methyl-N-alkylpyrrolidinium and quaternary ammonium cations : novel low cost ionic liquids, Green chemistry, vol. 4, no. 3, pp. 223-229, doi: 10.1039/B201063A. Attached Files Name Description MIMEType Size Downloads Title Methanesulfonate and p-toluenesulfonate salts of the N-methyl-N-alkylpyrrolidinium and quaternary ammonium cations : novel low cost ionic liquids Formatted title Methanesulfonate and p-toluenesulfonate salts of the N-methyl-N-alkylpyrrolidinium and quaternary ammonium cations : novel low cost ionic liquids Author(s) Golding, J. Forsyth, S. MacFarlane, D. R. Forsyth, M. orcid.org/0000-0002-4273-8105 Deacon, G. B. Journal name Green chemistry Volume number 4 Issue number 3 Start page 223 End page 229 Publisher Royal Society of Chemistry Place of publication London, England Publication date 2002 ISSN 1463-9262 1463-9270 Summary The preparation and characterization of a series of novel salts, based on the N-methyl-N-alkylpyrrolidinium or quaternary ammonium organic cations coupled with sulfonate type anions, namely the mesylate (CH3SO3−) and tosylate (CH3C6H4SO3−) anions are reported. These salts are analogues of the previously described organic cation bis(trifluoromethanesulfonyl)amide (TFSA) salts that form useful ionic liquids of interest in “Green” synthesis. Several of the salts are liquid below 50 °C, e.g. tributylhexylammonium tosylate and ethylmethylpyrrolidinium mesylate and one is liquid at and below room temperature (tributylhexylammonium mesylate). These new salts have a cost advantage over salts of the TFSA−, PF6− and CF3SO3− anions. Electrochemical and thermal properties have been investigated. The salts are stable to beyond 100 °C and exhibit electrochemical potential windows of at least ±2 V vs. Ag/Ag+. Some of the salts exhibit multiple crystalline phases below their melting points, potentially indicative of plastic crystal behaviour, whilst others showed more simple solid–liquid behaviour. Many of the salts were found to be glass forming. Language eng DOI 10.1039/B201063A Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2002, The Royal Society of Chemistry Persistent URL http://hdl.handle.net/10536/DRO/DU:30030160 Document type: Journal Article Collections: Institute for Technology Research and Innovation GTP Research Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 10 Sep 2010, 15:09:29 EST Mon, 18 Oct 2010, 08:36:37 EST Mon, 18 Oct 2010, 08:38:23 EST Mon, 16 Jun 2014, 16:25:13 EST Filtered Full Citation counts:   Cited 101 times in TR Web of Science Cited 107 times in Scopus Search Google Scholar Access Statistics: 898 Abstract Views, 0 File Downloads  -  Detailed Statistics Created: Fri, 10 Sep 2010, 15:09:28 EST

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