Plasticizer effects in polyether electrolytes studied by positron annihilation lifetime spectroscopy

Hill, A. J., MacFarlane, D. R., Li, J., Jones, P. L. and Forsyth, M. 1998, Plasticizer effects in polyether electrolytes studied by positron annihilation lifetime spectroscopy, Electrochimica acta, vol. 43, no. 10-11, pp. 1481-1484.

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Title Plasticizer effects in polyether electrolytes studied by positron annihilation lifetime spectroscopy
Author(s) Hill, A. J.
MacFarlane, D. R.
Li, J.
Jones, P. L.
Forsyth, M.
Journal name Electrochimica acta
Volume number 43
Issue number 10-11
Start page 1481
End page 1484
Publisher Elsevier Science Pub. Co.
Place of publication New York, N.Y.
Publication date 1998-04
ISSN 0013-4686
1873-3859
Keyword(s) polyether
electrolyte
positron
plasticizer
Summary Positron annihilation lifetime spectroscopy (PALS) has been used to probe the effects on free volume of the addition of either propylene carbonate or tetraglyme to a polyether-based electrolyte. Despite their very different behaviour as observed by NMR and conductivity measurement, the PALS sensitive free volume of the samples changes in a similar way on addition of the two plasticizers. It is concluded that the effect of these plasticizers on conductivity is determined more by their effect on ion-polymer and ion-ion interactions than by their effect on the PALS free volume.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©1998, Elsevier Science Ltd.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030164

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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