An investigation of a phosphinate-based ionic liquid for corrosion protection of magnesium alloy AZ31 Howlett, Patrick C., Zhang, Stephen, MacFarlane, Douglas R. and Forsyth, Maria 2007, An investigation of a phosphinate-based ionic liquid for corrosion protection of magnesium alloy AZ31, Australian journal of chemistry, vol. 60, no. 1, pp. 43-46, doi: 10.1071/CH06340. Attached Files Name Description MIMEType Size Downloads Title An investigation of a phosphinate-based ionic liquid for corrosion protection of magnesium alloy AZ31 Author(s) Howlett, Patrick C. orcid.org/0000-0002-2151-2932 Zhang, Stephen MacFarlane, Douglas R. Forsyth, Maria orcid.org/0000-0002-4273-8105 Journal name Australian journal of chemistry Volume number 60 Issue number 1 Start page 43 End page 46 Publisher CSIRO Place of publication Melbourne, Vic. Publication date 2007 ISSN 0004-9425 1445-0038 Summary This work reports a preliminary exploration of the potential of the ionic liquid trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate (P6,6,6,14M3PPh) for use as a conversion coating agent for corrosion protection of magnesium alloy AZ31. Results obtained for the as received IL did not indicate any measureable improvement in protection. However, when the IL was allowed to reach equilibrium/saturation with moisture from the atmosphere, treatment with this ‘wet’ solution resulted in a substantial improvement in corrosion resistance. Preliminary electrochemical, optical, and spectroscopic characterization of the film will be presented along with a possible mechanism for film formation. Language eng DOI 10.1071/CH06340 Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2007, CSIRO Persistent URL http://hdl.handle.net/10536/DRO/DU:30030169 Document type: Journal Article Collection: Institute for Technology Research and Innovation Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 10 Sep 2010, 15:09:37 EST Mon, 20 Sep 2010, 11:14:29 EST Mon, 20 Sep 2010, 11:16:03 EST Thu, 09 Jan 2014, 10:41:51 EST Mon, 16 Jun 2014, 16:25:47 EST Filtered Full Citation counts:   Cited 30 times in TR Web of Science Cited 42 times in Scopus Search Google Scholar Access Statistics: 542 Abstract Views, 0 File Downloads  -  Detailed Statistics Created: Fri, 10 Sep 2010, 15:09:37 EST

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