Synthesis and characterisation of rare earth complexes supported by para-substituted Cinnamate Ligands

Deacon, Glen B., Forsyth, Maria, Junk, Peter C., Leary, Stuart G. and Lee, Winnie W. 2009, Synthesis and characterisation of rare earth complexes supported by para-substituted Cinnamate Ligands, Zeitschrift für anorganische chemie, vol. 635, no. 6-7, pp. 833-839.

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Title Synthesis and characterisation of rare earth complexes supported by para-substituted Cinnamate Ligands
Formatted title Synthesis and characterisation of rare earth complexes supported by para-substituted Cinnamate Ligands
Author(s) Deacon, Glen B.
Forsyth, Maria
Junk, Peter C.
Leary, Stuart G.
Lee, Winnie W.
Journal name Zeitschrift für anorganische chemie
Volume number 635
Issue number 6-7
Start page 833
End page 839
Total pages 7
Publisher Wiley
Place of publication Leipzig, Germany
Publication date 2009
ISSN 0044-2313
1521-3749
Keyword(s) lanthanides
cinnamates
x-ray diffraction
rare earth compounds
Summary The preparations and characterisations of a range of lanthanoid 4-(R)-substituted (4-Rcinn, R = OH, OMe, NO2, Cl), known to have good anticorrosion properties, are reported. The crystal structure of [Ce(4-OHcinn)3(MeOH)2(H2O)]·MeOH is a polymer, in which the cerium atoms are nonacoordinate, and adjacent cerium atoms are bridged by either two bridging bidentate or two bridging tridentate carboxylate ligands. Each cerium atom also has one monodentate 4-hydroxycinnamate ligand, one aqua ligand, and two methanol ligands.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2009 Wiley-VCH Verlag GmbH & Co. KGaA
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030179

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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