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Ionic conduction in doped succinonitrile

Long, S., MacFarlane, D. R. and Forsyth, M. 2004, Ionic conduction in doped succinonitrile, Solid state ionics, vol. 175, no. 1-4, pp. 733-738.

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Title Ionic conduction in doped succinonitrile
Author(s) Long, S.
MacFarlane, D. R.
Forsyth, M.
Journal name Solid state ionics
Volume number 175
Issue number 1-4
Start page 733
End page 738
Publisher Elsevier
Place of publication Amsterdam, The Netherlands
Publication date 2004-11-30
ISSN 0167-2738
1872-7689
Keyword(s) molecular plastic crystals
ionic conductivity
diffusion
solid electrolytes
lithium
Summary Doping of lithium salts into the plastic crystal phase of succinonitrile does significantly increase ionic conductivity. This paper investigates the effect of anion (TFSA, Tf and BF4) on the conductivity and diffusion of the mobile species using impedance spectroscopy and NMR. Room temperature conductivities up to 2.1×10−4 S cm−1 were obtained with 1 mol% lithium bis(trifluoromethanesulfonyl)amide in succinonitrile. Pulse field gradient NMR has shown that in all three systems investigated, both cation and anion are mobile in this lattice.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2004, Elsevier B.V.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030183

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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