Plastic crystal electrolyte materials : new perspectives on solid state ionics MacFarlane, Douglas R. and Forsyth, Maria 2001, Plastic crystal electrolyte materials : new perspectives on solid state ionics, Advanced materials, vol. 13, no. 12-13, pp. 957-966, doi: 10.1002/1521-4095(200107)13:12/13<957::AID-ADMA957>3.0.CO;2-#. Attached Files Name Description MIMEType Size Downloads Title Plastic crystal electrolyte materials : new perspectives on solid state ionics Author(s) MacFarlane, Douglas R. Forsyth, Maria orcid.org/0000-0002-4273-8105 Journal name Advanced materials Volume number 13 Issue number 12-13 Start page 957 End page 966 Publisher Wiley-VCH Place of publication Weinheim, Germany Publication date 2001-07 ISSN 0935-9648 1521-4095 Keyword(s) conductivity Ethylmethylpyrrolidinium bis(trifluoromethanesulfonyl)amide (P12TFSA) nuclear magnetic resonanz (NMR) plastic crystals solid electrolytes solid-state ion conductors Summary Plastic crystal materials have long been known but have only relatively recently become of interest as solid–state ion conductors. Their properties are often associated with dynamic orientational disorder or rotator motions in the crystalline lattice. This paper describes recent work in the field including the range of organic ionic compounds that exhibit ion conduction at room temperature. Conductivity in some cases is high enough to render the compounds of interest as electrolyte materials in all solid state electrochemical devices. Doping of the plastic crystal phase with a small ion such as Li+ in some cases produces an even higher conductivity. In this case the plastic crystal acts as a solid state “solvent” for the doped ion and supports the conductive motion of the dopant via motions of the matrix ions. These doped materials are also described in detail. Language eng DOI 10.1002/1521-4095(200107)13:12/13<957::AID-ADMA957>3.0.CO;2-# Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2001, Wiley Persistent URL http://hdl.handle.net/10536/DRO/DU:30030190 Document type: Journal Article Collection: Institute for Technology Research and Innovation Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 10 Sep 2010, 15:09:58 EST Wed, 13 Oct 2010, 08:29:47 EST Wed, 13 Oct 2010, 08:33:06 EST Mon, 16 Jun 2014, 16:26:54 EST Wed, 18 Nov 2015, 08:23:14 EST Filtered Full Citation counts:   Cited 0 times in TR Web of Science Cited 215 times in Scopus Search Google Scholar Access Statistics: 481 Abstract Views, 0 File Downloads  -  Detailed Statistics Created: Fri, 10 Sep 2010, 15:09:58 EST

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