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Plastic crystal electrolyte materials : new perspectives on solid state ionics

MacFarlane, Douglas R. and Forsyth, Maria 2001, Plastic crystal electrolyte materials : new perspectives on solid state ionics, Advanced materials, vol. 13, no. 12-13, pp. 957-966, doi: 10.1002/1521-4095(200107)13:12/13<957::AID-ADMA957>3.0.CO;2-#.

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Title Plastic crystal electrolyte materials : new perspectives on solid state ionics
Author(s) MacFarlane, Douglas R.
Forsyth, MariaORCID iD for Forsyth, Maria
Journal name Advanced materials
Volume number 13
Issue number 12-13
Start page 957
End page 966
Publisher Wiley-VCH
Place of publication Weinheim, Germany
Publication date 2001-07
ISSN 0935-9648
Keyword(s) conductivity
Ethylmethylpyrrolidinium bis(trifluoromethanesulfonyl)amide (P12TFSA)
nuclear magnetic resonanz (NMR)
plastic crystals
solid electrolytes
solid-state ion conductors
Summary Plastic crystal materials have long been known but have only relatively recently become of interest as solid–state ion conductors. Their properties are often associated with dynamic orientational disorder or rotator motions in the crystalline lattice. This paper describes recent work in the field including the range of organic ionic compounds that exhibit ion conduction at room temperature. Conductivity in some cases is high enough to render the compounds of interest as electrolyte materials in all solid state electrochemical devices. Doping of the plastic crystal phase with a small ion such as Li+ in some cases produces an even higher conductivity. In this case the plastic crystal acts as a solid state “solvent” for the doped ion and supports the conductive motion of the dopant via motions of the matrix ions. These doped materials are also described in detail.
Language eng
DOI 10.1002/1521-4095(200107)13:12/13<957::AID-ADMA957>3.0.CO;2-#
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2001, Wiley
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Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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