Electrochemical synthesis of polypyrrole in ionic liquids

Pringle, Jennifer M., Efthimiadis, John, Howlett, Patrick C., Efthimiadis, Jim, MacFarlane, Douglas R., Chaplin, Adrian B., Hall, Simon B., Officer, David L., Wallace, Gordon G. and Forsyth, Maria 2004, Electrochemical synthesis of polypyrrole in ionic liquids, Polymer, vol. 45, no. 5, pp. 1447-1453, doi: 10.1016/j.polymer.2004.01.006.

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Title Electrochemical synthesis of polypyrrole in ionic liquids
Author(s) Pringle, Jennifer M.ORCID iD for Pringle, Jennifer M. orcid.org/0000-0002-2729-2838
Efthimiadis, John
Howlett, Patrick C.ORCID iD for Howlett, Patrick C. orcid.org/0000-0002-2151-2932
Efthimiadis, Jim
MacFarlane, Douglas R.
Chaplin, Adrian B.
Hall, Simon B.
Officer, David L.
Wallace, Gordon G.
Forsyth, MariaORCID iD for Forsyth, Maria orcid.org/0000-0002-4273-8105
Journal name Polymer
Volume number 45
Issue number 5
Start page 1447
End page 1453
Publisher Elsevier
Place of publication Oxford, England
Publication date 2004-03
ISSN 0032-3861
Keyword(s) polypyrrole
ionic liquids
conducting polymers
Summary Electrochemical synthesis of inherently conducting polymers such as polypyrrole is traditionally performed in a molecular solvent/electrolyte system such acetonitrile/lithium perchlorate. We report the use of ionic liquids 1-butyl-3-methylimidazolium hexafluorophosphate, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl) amide and N,N-butylmethylpyrrolidinium bis(trifluoromethanesulfonyl) amide, both as the growth medium and as an electrolyte for the electrochemical cycling of polypyrrole films. Use of the ionic liquid as the growth medium results in significantly altered film morphologies and improved electrochemical activities.
Language eng
DOI 10.1016/j.polymer.2004.01.006
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2004, Elsevier
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030236

Document type: Journal Article
Collections: Institute for Technology Research and Innovation
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