Acid–organic base swollen polymer membranes

Sun, Jiazeng, Jordan, L. R., Forsyth, M. and MacFarlane, D. R. 2001, Acid–organic base swollen polymer membranes, Electrochimica acta, vol. 46, no. 10-11, pp. 1703-1708, doi: 10.1016/S0013-4686(00)00774-X.

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Title Acid–organic base swollen polymer membranes
Author(s) Sun, Jiazeng
Jordan, L. R.
Forsyth, M.ORCID iD for Forsyth, M.
MacFarlane, D. R.
Journal name Electrochimica acta
Volume number 46
Issue number 10-11
Start page 1703
End page 1708
Publisher Elsevier Science Pub. Co.
Place of publication New York, N.Y.
Publication date 2001-03-15
ISSN 0013-4686
Keyword(s) nafion117
imidazolium salts
proton conductivity
Summary In this work, two different polymer membrane systems based on Nafion and Teflon were investigated as proton conductors for polymer membrane fuel cells. Water-free Nafion117 membranes swollen with different non-aqueous solvents were prepared. The solvents included imidazole, imidazole–imidazolium salt solutions, room temperature molten salts and molten salt–acid solutions. Teflon films were treated with a surfactant, or a Nafion solution, to improve their surface properties, and were subsequently swollen with phosphoric acid. Conductivity measurements were carried out on both the Nafion and Teflon membranes. Conductivities in the range of 10−3 S cm−1 at around 100°C were obtained. This is still an order of magnitude lower than the corresponding water swollen Nafion at 80°C.
Language eng
DOI 10.1016/S0013-4686(00)00774-X
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2001, Elsevier Science Ltd.
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