Poly methacrylate-plasticiser-salt blends as solid polymer electrolytes

Sun, Jiazeng, MacFarlane, D. R. and Forsyth, M. 1995, Poly methacrylate-plasticiser-salt blends as solid polymer electrolytes, Electrochimica acta, vol. 40, no. 13-14, pp. 2301-2304.

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Title Poly methacrylate-plasticiser-salt blends as solid polymer electrolytes
Author(s) Sun, Jiazeng
MacFarlane, D. R.
Forsyth, M.
Journal name Electrochimica acta
Volume number 40
Issue number 13-14
Start page 2301
End page 2304
Publisher Elsevier Science Pub. Co.
Place of publication New York, N.Y.
Publication date 1995-10
ISSN 0013-4686
1873-3859
Keyword(s) poly(ethylene glycol methacrylate)
polymer electrolyte
ionic conductivity
glass transition temperature
plasticiser
lithium perchlorate
Summary Methoxy-ethylene glycol methacrylates, CH2=CMeCOO(CH2CH2O)nMe (n = 1, 2, 3), ethoxy-triethylene glycol methacrylate, CH2=CMeCOO(CH2CH2O)3Et, and N,N-dimethylaminoethyl methacrylate, CH2=CMeCOOCH2CH2NMe2, were used to synthesise the corresponding polymers. Conductivities of these polymers complexed with lithium perchlorate were investigated. Tetraethylene glycol dimethyl ether was used as plasticiser to increase the conductivity of the materials. A conductivity of 10−5 S cm−1 was obtained at room temperature for the plasticised polymer samples. Effects of polymer structure, plasticiser, salt concentration and temperature on conductivity and glass transition temperature of the polymer electrolytes are discussed.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©1995, Elsevier Science Ltd.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030266

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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