Conductive plastic crystal phases of the 1-alkyl-2-methyl pyrrolinium TFSA salts

Sun, J., MacFarlane, D. R. and Forsyth, M. 2002, Conductive plastic crystal phases of the 1-alkyl-2-methyl pyrrolinium TFSA salts, Solid state ionics, vol. 148, no. 1-2, pp. 145-151, doi: 10.1016/S0167-2738(02)00057-7.

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Title Conductive plastic crystal phases of the 1-alkyl-2-methyl pyrrolinium TFSA salts
Author(s) Sun, J.
MacFarlane, D. R.
Forsyth, M.ORCID iD for Forsyth, M.
Journal name Solid state ionics
Volume number 148
Issue number 1-2
Start page 145
End page 151
Publisher Elsevier
Place of publication Amsterdam, The Netherlands
Publication date 2002-05-01
ISSN 0167-2738
Keyword(s) 1-Alkyl-2-methyl pyrrolinium bis(trifluoromethane sulfonyl) amide
plastic crystal
Summary Characterization of a new family of salts, based on a number of 1-alkyl-2-methyl pyrrolinium cations and the bis(trifluoromethane sulfonyl) amide anion (TFSA), is presented. From the thermal analysis, conductivity and X-ray diffraction (XRD) measurements, at least one of the compounds of the family, 1-ethyl-2-methyl pyrrolinium TFSA, was found to exhibit plastic crystal phases before melting and to exhibit high conductivity in the solid state (1×10−4 S cm−1 at 25 °C). This plastic crystal behaviour is discussed in comparison with other members of this pyrrolinium salt family.
Language eng
DOI 10.1016/S0167-2738(02)00057-7
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2002, Elsevier Science B.V.
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