Conductive plastic crystal phases of the 1-alkyl-2-methyl pyrrolinium TFSA salts

Sun, J., MacFarlane, D. R. and Forsyth, M. 2002, Conductive plastic crystal phases of the 1-alkyl-2-methyl pyrrolinium TFSA salts, Solid state ionics, vol. 148, no. 1-2, pp. 145-151.

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Title Conductive plastic crystal phases of the 1-alkyl-2-methyl pyrrolinium TFSA salts
Author(s) Sun, J.
MacFarlane, D. R.
Forsyth, M.
Journal name Solid state ionics
Volume number 148
Issue number 1-2
Start page 145
End page 151
Publisher Elsevier
Place of publication Amsterdam, The Netherlands
Publication date 2002-05-01
ISSN 0167-2738
1872-7689
Keyword(s) 1-Alkyl-2-methyl pyrrolinium bis(trifluoromethane sulfonyl) amide
plastic crystal
conductivity
DSC
XRD
Summary Characterization of a new family of salts, based on a number of 1-alkyl-2-methyl pyrrolinium cations and the bis(trifluoromethane sulfonyl) amide anion (TFSA), is presented. From the thermal analysis, conductivity and X-ray diffraction (XRD) measurements, at least one of the compounds of the family, 1-ethyl-2-methyl pyrrolinium TFSA, was found to exhibit plastic crystal phases before melting and to exhibit high conductivity in the solid state (1×10−4 S cm−1 at 25 °C). This plastic crystal behaviour is discussed in comparison with other members of this pyrrolinium salt family.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2002, Elsevier Science B.V.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030271

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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