A new family of ionic liquids based on the 1-alkyl-2-methyl pyrrolinium cation

Sun, J., MacFarlane, D. R. and Forsyth, M. 2003, A new family of ionic liquids based on the 1-alkyl-2-methyl pyrrolinium cation, Electrochimica acta, vol. 48, no. 12, pp. 1707-1711.

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Title A new family of ionic liquids based on the 1-alkyl-2-methyl pyrrolinium cation
Author(s) Sun, J.
MacFarlane, D. R.
Forsyth, M.
Journal name Electrochimica acta
Volume number 48
Issue number 12
Start page 1707
End page 1711
Publisher Elsevier Science Pub. Co.
Place of publication New York, N.Y.
Publication date 2003-05-30
ISSN 0013-4686
1873-3859
Keyword(s) 1-Alkyl-2-methyl pyrrolinium cation
ionic liquids
conductivity
electrochemical window
TGA
Summary Five new salts based on 1-alkyl-2-methyl pyrrolinium ion are reported, two involving the iodide ion and three involving the bis(trifluoromethanesulfonyl) amide ion. The iodide salts have melting points around 100 °C, while the amide salts have melting points around room temperature. Two of the amide salts can be easily quenched into the glassy state and exhibit glass transition temperatures around −70 °C. The 2-methyl pyrrolinium cation bears structural similarities to the aromatic imidazolium cations on one hand and the cyclic ammonium cation family based on the pyrrolidinium cation on the other. The properties of the salts reported here are compared within these two related families of salts.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2003, Elsevier Science Ltd.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030273

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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