A new Lewis-base ionic liquid comprising a mono-charged diamine structure : a highly stable electrolyte for lithium electrochemistry

Yoshizawa-Fujita, Masahiro, MacFarlane, Douglas R., Howlett, Patrick C. and Forsyth, Maria 2006, A new Lewis-base ionic liquid comprising a mono-charged diamine structure : a highly stable electrolyte for lithium electrochemistry, Electrochemistry communications, vol. 8, no. 3, pp. 445-449.

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Title A new Lewis-base ionic liquid comprising a mono-charged diamine structure : a highly stable electrolyte for lithium electrochemistry
Author(s) Yoshizawa-Fujita, Masahiro
MacFarlane, Douglas R.
Howlett, Patrick C.
Forsyth, Maria
Journal name Electrochemistry communications
Volume number 8
Issue number 3
Start page 445
End page 449
Publisher Elsevier
Place of publication Amsterdam, The Netherlands
Publication date 2006-03
ISSN 1388-2481
1873-1902
Keyword(s) ionic liquid
lewis base
lithium electrochemistry
ionic conductivity
Summary A new Lewis-base ionic liquid (IL) based on mono-charged 1,4-diazabicyclo[2.2.2]octane (dabco) was synthesized and its thermal and electrochemical behaviour was characterized. The dabco-based IL with bis(trifluoromethanesulfonyl)amide (TFSA) anion melts at 76 °C when the N-substituted alkyl chain length is 2. The dabco-based IL showed a wide electrochemical window of over 4 V ranging from −3.5 to +1.5 V vs. Fc/Fc+ and was able to deposit and strip lithium from a nickel substrate at reasonable efficiency.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2006, Elsevier B.V.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030298

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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