Boroxine ring compounds as dissociation enhancers in gel polyelectrolytes

Zhou, F., MacFarlane, D. R. and Forsyth, M. 2003, Boroxine ring compounds as dissociation enhancers in gel polyelectrolytes, Electrochimica acta, vol. 48, no. 12, pp. 1749-1758.

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Title Boroxine ring compounds as dissociation enhancers in gel polyelectrolytes
Author(s) Zhou, F.
MacFarlane, D. R.
Forsyth, M.
Journal name Electrochimica acta
Volume number 48
Issue number 12
Start page 1749
End page 1758
Publisher Elsevier Science Pub. Co.
Place of publication New York, N.Y.
Publication date 2003-05-30
ISSN 0013-4686
1873-3859
Keyword(s) boroxine
conductivity
polyelectrolyte
gel electrolyte
7Li and 11B NMR
Summary In order to combine the advantages of both traditional gel electrolytes and polyelectrolytes, a novel polyelectrolyte which incorporates a boroxine ring-containing anion-trapping agent has been explored. Poly(lithium 2-acrylamido-2-methyl-1-propanesulfonate) (PAMPSLi), ethylene carbonate (EC) and tri(methoxyethoxyethoxyethoxy)boroxine (TME3Bx) were combined to prepare various gel systems. The thermal properties and conductivities of these gels have been investigated. A conductivity of 10−3.6 S cm−1 at 20 °C has been achieved in a gel polyelectrolyte system with a molar ratio of [EC]:[TME3Bx]:[Li+]=24:1.7:1. Temperature-dependent NMR measurements indicated that a significant interaction exists between the boroxine ring and the polyelectrolyte.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2003, Elsevier Science Ltd.
Persistent URL http://hdl.handle.net/10536/DRO/DU:30030300

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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