DRO

Lithium-functionalised silica nanoparticles for enhanced ionic conductivity in an organic ionic plastic crystal

Shekibi, Youssof, Pringle, Jennifer M., Sun, Jiazeng, Pas, Steven J., Rocher, Nathalie M., Clare, Bronya R., Hill, Anita J., MacFarlane, Douglas R. and Forsyth, Maria 2010, Lithium-functionalised silica nanoparticles for enhanced ionic conductivity in an organic ionic plastic crystal, Journal of materials chemistry, vol. 20, no. 2, pp. 338-344.

Attached Files
Name Description MIMEType Size Downloads

Title Lithium-functionalised silica nanoparticles for enhanced ionic conductivity in an organic ionic plastic crystal
Author(s) Shekibi, Youssof
Pringle, Jennifer M.
Sun, Jiazeng
Pas, Steven J.
Rocher, Nathalie M.
Clare, Bronya R.
Hill, Anita J.
MacFarlane, Douglas R.
Forsyth, Maria
Journal name Journal of materials chemistry
Volume number 20
Issue number 2
Start page 338
End page 344
Total pages 7
Publisher Royal Society of Chemistry
Place of publication Cambridge, England
Publication date 2010
ISSN 0959-9428
1364-5501
Summary Addition of silica nanoparticles functionalised with lithium propane sulfonate to the organic ionic plastic crystal N-ethyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)amide ([C2mpyr][NTf2]) results in a significant increase in ionic conductivity. Analysis of these nanocomposites by impedance spectroscopy, NMR, positron annihilation lifetime spectroscopy (PALS) and Raman spectroscopy suggests that this is the result of higher matrix mobility due to an increase in defect size and concentration. The effect of these functionalised nanoparticles is compared to that previously observed for unfunctionalised nanoparticles in the lithium-doped and pure plastic crystal.
Language eng
Field of Research 091205 Functional Materials
030399 Macromolecular and Materials Chemistry not elsewhere classified
030607 Transport Properties and Non-equilibrium Processes
Socio Economic Objective 850602 Energy Storage (excl. Hydrogen)
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2010, Royal Society of Chemistry
Persistent URL http://hdl.handle.net/10536/DRO/DU:30031079

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
Connect to link resolver
 
Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved.

Versions
Version Filter Type
Citation counts: TR Web of Science Citation Count  Cited 11 times in TR Web of Science
Scopus Citation Count Cited 12 times in Scopus
Google Scholar Search Google Scholar
Access Statistics: 285 Abstract Views, 1 File Downloads  -  Detailed Statistics
Created: Mon, 08 Nov 2010, 09:59:52 EST by Leanne Swaneveld

Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.