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Unusual phase behaviour of the organic ionic plastic crystal N,N-dimethylpyrrolidinium tetrafluoroborate

Pringle, Jennifer M., Adebahr, Josefina, MacFarlane, Douglas R. and Forsyth, Maria 2010, Unusual phase behaviour of the organic ionic plastic crystal N,N-dimethylpyrrolidinium tetrafluoroborate, Physical chemistry chemical physics, vol. 12, no. 26, pp. 7234-7240.

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Title Unusual phase behaviour of the organic ionic plastic crystal N,N-dimethylpyrrolidinium tetrafluoroborate
Formatted title Unusual phase behaviour of the organic ionic plastic crystal N,N-dimethylpyrrolidinium tetrafluoroborate
Author(s) Pringle, Jennifer M.
Adebahr, Josefina
MacFarlane, Douglas R.
Forsyth, Maria
Journal name Physical chemistry chemical physics
Volume number 12
Issue number 26
Start page 7234
End page 7240
Publisher Royal Society of Chemistry
Place of publication Cambridge, England
Publication date 2010
ISSN 1463-9076
1463-9084
Summary Analysis of N,N-dimethylpyrrolidinium tetrafluoroborate by 1H and 11B NMR, Raman spectroscopy and powder XRD shows that this organic ionic plastic crystal material exhibits unusual phase behaviour. 1H NMR analysis indicates that the mobility of the pyrrolidinium cation decreases when the material is heated into phase I, while the X-ray diffraction pattern changes from a simple, one peak structure in phase II to a more complex pattern in phase I. The possible origins of these unusual transitions are discussed.
Language eng
Field of Research 030399 Macromolecular and Materials Chemistry not elsewhere classified
030604 Electrochemistry
Socio Economic Objective 850602 Energy Storage (excl. Hydrogen)
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2010, Owner Societies
Persistent URL http://hdl.handle.net/10536/DRO/DU:30031088

Document type: Journal Article
Collection: Institute for Technology Research and Innovation
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Created: Mon, 08 Nov 2010, 11:55:39 EST by Leanne Swaneveld