Unusual phase behaviour of the organic ionic plastic crystal N,N-dimethylpyrrolidinium tetrafluoroborate Pringle, Jennifer M., Adebahr, Josefina, MacFarlane, Douglas R. and Forsyth, Maria 2010, Unusual phase behaviour of the organic ionic plastic crystal N,N-dimethylpyrrolidinium tetrafluoroborate, Physical chemistry chemical physics, vol. 12, no. 26, pp. 7234-7240, doi: 10.1039/B925501J. Attached Files Name Description MIMEType Size Downloads Title Unusual phase behaviour of the organic ionic plastic crystal N,N-dimethylpyrrolidinium tetrafluoroborate Formatted title Unusual phase behaviour of the organic ionic plastic crystal N,N-dimethylpyrrolidinium tetrafluoroborate Author(s) Pringle, Jennifer M. orcid.org/0000-0002-2729-2838 Adebahr, Josefina MacFarlane, Douglas R. Forsyth, Maria orcid.org/0000-0002-4273-8105 Journal name Physical chemistry chemical physics Volume number 12 Issue number 26 Start page 7234 End page 7240 Total pages 7 Publisher Royal Society of Chemistry Place of publication Cambridge, England Publication date 2010 ISSN 1463-9076 1463-9084 Summary Analysis of N,N-dimethylpyrrolidinium tetrafluoroborate by 1H and 11B NMR, Raman spectroscopy and powder XRD shows that this organic ionic plastic crystal material exhibits unusual phase behaviour. 1H NMR analysis indicates that the mobility of the pyrrolidinium cation decreases when the material is heated into phase I, while the X-ray diffraction pattern changes from a simple, one peak structure in phase II to a more complex pattern in phase I. The possible origins of these unusual transitions are discussed. Language eng DOI 10.1039/B925501J Field of Research 030399 Macromolecular and Materials Chemistry not elsewhere classified 030604 Electrochemistry Socio Economic Objective 850602 Energy Storage (excl. Hydrogen) HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2010, Owner Societies Persistent URL http://hdl.handle.net/10536/DRO/DU:30031088 Document type: Journal Article Collection: Institute for Technology Research and Innovation Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Mon, 08 Nov 2010, 11:55:40 EST Mon, 08 Nov 2010, 12:01:08 EST Mon, 08 Nov 2010, 12:02:37 EST Wed, 30 Apr 2014, 14:52:40 EST Fri, 10 Oct 2014, 08:43:33 EST Thu, 11 Dec 2014, 16:48:41 EST Filtered Full Citation counts:   Cited 17 times in TR Web of Science Cited 18 times in Scopus Search Google Scholar Access Statistics: 431 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Mon, 08 Nov 2010, 11:55:39 EST by Leanne Swaneveld

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