Autocatalytic nature of permanganate oxidations exploited for highly sensitive chemiluminescence detection

Slezak, Teo, Terry, Jessica M., Francis, Paul S., Hindson, Christopher M., Olson, Don C., Wolcott, Duane K. and Barnett, Neil W. 2010, Autocatalytic nature of permanganate oxidations exploited for highly sensitive chemiluminescence detection, Analytical chemistry, vol. 82, no. 6, pp. 2580-2584.

Attached Files
Name Description MIMEType Size Downloads

Title Autocatalytic nature of permanganate oxidations exploited for highly sensitive chemiluminescence detection
Author(s) Slezak, Teo
Terry, Jessica M.
Francis, Paul S.
Hindson, Christopher M.
Olson, Don C.
Wolcott, Duane K.
Barnett, Neil W.
Journal name Analytical chemistry
Volume number 82
Issue number 6
Start page 2580
End page 2584
Total pages 5
Publisher American Chemical Society
Place of publication Washington, D.C.
Publication date 2010-03-15
ISSN 0003-2700
1520-6882
Summary Manganese(II) salts catalyze the chemiluminescent oxidation of organic compounds with acidic potassium permanganate. The formation of insoluble manganese(IV) species from the reaction between manganese(II) and permanganate can be prevented with sodium polyphosphate, and therefore, relatively high concentrations of the catalyst can be added to the reagent before the lightproducing reaction is initiated. The rapid and intense emissions from these manganese(II) catalyzed chemiluminescence reactions provide highly sensitive detection and greater compatibility with liquid chromatography.
Notes Publication Date (Web): February 17, 2010
Language eng
Field of Research 030101 Analytical Spectrometry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
HERDC collection year 2010
Copyright notice ©2010, American Chemical Society
Persistent URL http://hdl.handle.net/10536/DRO/DU:30031408

Connect to link resolver
 
Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved.

Versions
Version Filter Type
Citation counts: TR Web of Science Citation Count  Cited 19 times in TR Web of Science
Scopus Citation Count Cited 20 times in Scopus
Google Scholar Search Google Scholar
Access Statistics: 300 Abstract Views, 4 File Downloads  -  Detailed Statistics
Created: Wed, 01 Dec 2010, 10:32:57 EST by Teresa Treffry

Every reasonable effort has been made to ensure that permission has been obtained for items included in DRO. If you believe that your rights have been infringed by this repository, please contact drosupport@deakin.edu.au.