Ionic liquid-assisted synthesis of polyaniline/gold nanocomposite and its biocatalytic application
Yang, Wenrong, Liu, Jingquan, Zheng, Rongkun, Liu, Zongwen, Dai, Yun, Chen, Guonan, Ringer, Simon and Braet, Filip 2008, Ionic liquid-assisted synthesis of polyaniline/gold nanocomposite and its biocatalytic application, Nanoscale research letters, vol. 3, no. 11, pp. 468-472.
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Ionic liquid-assisted synthesis of polyaniline/gold nanocomposite and its biocatalytic application
In this report, a novel chemical synthesis of polyaniline/gold nanocomposite is explored using ionic liquid (IL) 1-Butyl-3-methylimidazolium hexafluorophosphate. The direct chemical synthesis of polyaniline/gold nanocomposite was initiated via the spontaneous oxidation of aniline by AuCl4 − in IL. A nearly uniform dispersion of polyaniline/Au particles with a diameter of 450 ± 80 nm was produced by this method, which indicates that this method is more suitable for controlling particle dimensions. It was also found that the electrical conductivity of the polyaniline/gold nanocomposite was more than 100 times higher than that of the pure polyaniline nanoparticles. The polyaniline/gold nanocomposite displays superior function in the biocatalytic activation of microperoxidase-11 because of the high surface area of the assembly and the enhanced charge transport properties of the composite material. We also report the possible application of polyaniline/gold nanocomposite as a H2O2 biosensor.
Language
eng
Field of Research
100703 Nanobiotechnology
Socio Economic Objective
970103 Expanding Knowledge in the Chemical Sciences