Undoing lithium ion association in ionic liquids through the complexation by oligoethers Bayley, Paul M., Lane, G. H., Lyons, L. J., MacFarlane, D. R. and Forsyth, M. 2010, Undoing lithium ion association in ionic liquids through the complexation by oligoethers, Journal of physical chemistry C, vol. 114, no. 48, pp. 20569-20576, doi: 10.1021/jp104957j. Attached Files Name Description MIMEType Size Downloads Title Undoing lithium ion association in ionic liquids through the complexation by oligoethers Author(s) Bayley, Paul M. Lane, G. H. Lyons, L. J. MacFarlane, D. R. Forsyth, M. orcid.org/0000-0002-4273-8105 Journal name Journal of physical chemistry C Volume number 114 Issue number 48 Start page 20569 End page 20576 Total pages 8 Publisher American chemical society Place of publication Washington, D.C. Publication date 2010-12-09 ISSN 1520-6106 1520-5207 Summary Tetraglyme (TG) and the recently developed trimethylsilyl capped analogue (1NM3) when used as additives in a N-methyl-N-propylpyrrolidinium bis(trifluoromethylsulfonyl) amide [C3mpyr][NTf2]/0.65 M LiNTf2 electrolyte have been shown to dramatically enhance the transport properties of this electrolyte. In fact, at a concentration of 20 mol % tetraglyme (leading to a ratio of ~1:1 ether molecule per lithium ion), viscosity, conductivity, and the diffusion coefficients of the C3mpyr+ and NTf2− are practically reinstated to the values observed in the absence of lithium, thereby negating the structuring effects of the lithium ion. The 7Li T1 relaxation times also indicate that these additives strongly interact with the lithium ions. Furthermore, although TG has twice the viscosity of 1NM3, the greatest improvement in transport properties was observed for TG. Language eng DOI 10.1021/jp104957j Field of Research 091205 Functional Materials Socio Economic Objective 850602 Energy Storage (excl. Hydrogen) HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2010, American Chemical Society Persistent URL http://hdl.handle.net/10536/DRO/DU:30035814 Document type: Journal Article Collection: Institute for Technology Research and Innovation Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Fri, 24 Jun 2011, 10:37:11 EST Fri, 24 Jun 2011, 10:38:32 EST Mon, 18 Jul 2011, 14:48:34 EST Wed, 23 Apr 2014, 14:49:12 EST Mon, 16 Jun 2014, 18:29:46 EST Thu, 11 Dec 2014, 17:12:53 EST Filtered Full Citation counts:   Cited 20 times in TR Web of Science Cited 20 times in Scopus Search Google Scholar Access Statistics: 352 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Fri, 24 Jun 2011, 10:36:56 EST by Leanne Swaneveld

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