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Proton conductive composite membranes

Sunarso, J., Chen, C. Y., Tran, A. T. T., Wong, M. S. and Diniz da Costa, J. C. 2007, Proton conductive composite membranes, International journal of nanotechnology, vol. 4, no. 5, pp. 597-608, doi: 10.1504/IJNT.2007.014754.

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Title Proton conductive composite membranes
Author(s) Sunarso, J.
Chen, C. Y.
Tran, A. T. T.
Wong, M. S.
Diniz da Costa, J. C.
Journal name International journal of nanotechnology
Volume number 4
Issue number 5
Start page 597
End page 608
Publisher Inderscience Publishers
Place of publication Olney, England
Publication date 2007
ISSN 1475-7435
1741-8151
Keyword(s) particles
polymer matrix
composite membranes
proton conduction
metal alkoxides
sol gel
nanoparticles
nanotechnology
titania phosphate
fuel cells.
Summary In this work we investigated the synthesis of composite organic and inorganic membranes for proton conduction. Particles derived from metal alkoxides (M(OR)n) sol-gel processes (Ti, Zr, W with phosphoric acid) were embedded in polymeric matrices of poly-vinyl alcohol, (3-glycidoxypropyl)-trimethoxysilane and ethylene glycol. The structure of the composite membranes was complex as several IR peaks were convoluted, indicating the assignment of several functional groups. However, the peaks assigned to OH groups reduced in intensity in the composite membranes, indicating that cross-linking of hydroxyl groups in the organic and inorganic phases of the membrane may have occurred. The particles allowed for re-arrangement of the polymer matrix, as crystallinity was reduced compared to a polymer blank membrane. The composite membrane process resulted in homogeneous dispersion of nanoparticles into the polymer film. Proton conduction of the inorganic phase was mainly dominated by titania. Binary mixtures of titania phosphate (sample name TiP) resulted in proton conduction of 7.15 × 10−2 S.cm−1, one order of magnitude higher than zirconia phosphate (ZrP). The addition of Zr and W to TiP forming ternary or quaternary phases also led to lower proton conduction as compared to TiP. Similar trends were also observed for the composite membranes, though the TiP composite membrane proton conduction reduced after several hours of testing at 50°C, which was mainly attributed to acid leaching.
Language eng
DOI 10.1504/IJNT.2007.014754
Field of Research 109999 Technology not elsewhere classified
Socio Economic Objective 970110 Expanding Knowledge in Technology
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2007, Inderscience Enterprises
Persistent URL http://hdl.handle.net/10536/DRO/DU:30039090

Document type: Journal Article
Collection: Centre for Material and Fibre Innovation
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