Green chemiluminescence from a bis-cyclometalated iridium(III) complex with an ancillary bathophenanthroline disulfonate ligand
Zammit, Elizabeth M., Barnett, Neil W., Henderson, Luke C., Dyson, Gail A., Zhou, Ming and Francis, Paul S. 2011, Green chemiluminescence from a bis-cyclometalated iridium(III) complex with an ancillary bathophenanthroline disulfonate ligand, Analyst, vol. 136, no. 15, pp. 3069-3072.
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The reaction of a fluorinated iridium complex with cerium(IV) and organic reducing agents generates an intense emission with a significant hypsochromic shift compared to contemporary chemically-initiated luminescence from metal complexes.
Field of Research
030101 Analytical Spectrometry
Socio Economic Objective
970103 Expanding Knowledge in the Chemical Sciences
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