Polyterthiophene/CNT composite as a cathode material for lithium batteries employing an ionic liquid electrolyte Sivakkumar, S. R., Howlett, Patrick C., Winther-Jensen, Bjorn, Forsyth, Maria and MacFarlane, Douglas R. 2009, Polyterthiophene/CNT composite as a cathode material for lithium batteries employing an ionic liquid electrolyte, Electrochimica acta, vol. 54, no. 27, pp. 6844-6849, doi: 10.1016/j.electacta.2009.06.091. Attached Files Name Description MIMEType Size Downloads Title Polyterthiophene/CNT composite as a cathode material for lithium batteries employing an ionic liquid electrolyte Author(s) Sivakkumar, S. R. Howlett, Patrick C. orcid.org/0000-0002-2151-2932 Winther-Jensen, Bjorn Forsyth, Maria orcid.org/0000-0002-4273-8105 MacFarlane, Douglas R. Journal name Electrochimica acta Volume number 54 Issue number 27 Start page 6844 End page 6849 Total pages 6 Publisher Elsevier Place of publication New York, N.Y. Publication date 2009-11-30 ISSN 0013-4686 1873-3859 Keyword(s) conducting polymer cathode polythiophene polyterthiophene ionic liquid electrolyte lithium battery Summary A polyterthiophene (PTTh)/multi-walled carbon nanotube (CNT) composite was synthesised by in situ chemical polymerisation and used as an active cathode material in lithium cells assembled with an ionic liquid (IL) or conventional liquid electrolyte, LiBF4/EC–DMC–DEC. The IL electrolyte consisted of 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIBF4) containing LiBF4 and a small amount of vinylene carbonate (VC). The lithium cells were characterised by cyclic voltammetry (CV) and galvanostatic charge/discharge cycling. The specific capacity of the cells with IL and conventional liquid electrolytes after the 1st cycle was 50 and 47 mAh g−1 (based on PTTh weight), respectively at the C/5 rate. The capacity retention after the 100th cycle was 78% and 53%, respectively. The lithium cell assembled with a PTTh/CNT composite cathode and a non-flammable IL electrolyte exhibited a mean discharge voltage of 3.8 V vs Li+/Li and is a promising candidate for high-voltage power sources with enhanced safety. Language eng DOI 10.1016/j.electacta.2009.06.091 Field of Research 039999 Chemical Sciences not elsewhere classified Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences HERDC Research category C1.1 Refereed article in a scholarly journal Copyright notice ©2009, Elsevier Persistent URL http://hdl.handle.net/10536/DRO/DU:30040673 Document type: Journal Article Collections: Centre for Material and Fibre Innovation Institute for Technology Research and Innovation Related Links Link Description Connect to published version (restricted access) Go to link with your DU access privileges     Unless expressly stated otherwise, the copyright for items in DRO is owned by the author, with all rights reserved. Versions Version Filter Type Tue, 06 Dec 2011, 08:00:45 EST Tue, 06 Dec 2011, 08:07:56 EST Tue, 06 Dec 2011, 08:09:22 EST Thu, 09 Jan 2014, 10:57:18 EST Thu, 11 Dec 2014, 17:32:45 EST Filtered Full Citation counts:   Cited 24 times in TR Web of Science Cited 25 times in Scopus Search Google Scholar Access Statistics: 308 Abstract Views, 1 File Downloads  -  Detailed Statistics Created: Tue, 06 Dec 2011, 08:00:16 EST by Leanne Swaneveld

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