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Chemiluminescence from osmium(ii) complexes with phenanthroline, diphosphine and diarsine ligands

Zammit, Elizabeth M., Barbante, Gregory J., Carlson, Brenden, Doeven, Egan H., Barnett, Neil W., Hogan, Conor F., Richter, Mark M. and Francis, Paul S. 2012, Chemiluminescence from osmium(ii) complexes with phenanthroline, diphosphine and diarsine ligands, Analyst, vol. 137, no. 12, pp. 2766-2769.

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Title Chemiluminescence from osmium(ii) complexes with phenanthroline, diphosphine and diarsine ligands
Author(s) Zammit, Elizabeth M.
Barbante, Gregory J.
Carlson, Brenden
Doeven, Egan H.
Barnett, Neil W.
Hogan, Conor F.
Richter, Mark M.
Francis, Paul S.
Journal name Analyst
Volume number 137
Issue number 12
Start page 2766
End page 2769
Total pages 4
Publisher Royal Society of Chemistry
Place of publication Cambridge, England
Publication date 2012
ISSN 0003-2654
1364-5528
Summary The reaction of various [Os(L)2(L′)]2+ complexes (where L and L′ are phenanthroline, diphosphine or diarsine ligands) and organic reducing agents after chemical or electrochemical oxidation of the reactants produces an emission of light corresponding to MLCT transitions. In certain instances, the emission was greater than that of [Ru(bipy)3]2+, but the relative signals were dependent on many factors, including reagent concentration, mode of oxidation, reducing agent and the sensitivity of the photodetector over the wavelength range.
Language eng
Field of Research 030101 Analytical Spectrometry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2012, The Royal Society of Chemistry
Persistent URL http://hdl.handle.net/10536/DRO/DU:30047012

Document type: Journal Article
Collections: School of Life and Environmental Sciences
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