Concomitant reactivity of the m-Terphenylindium dihydroxide [2,6-Mes2C6H3In(OH)2]4 toward carbon dioxide and ethylene glycol

Ahmad, S. Usman, Beckmann, Jens and Duthie, Andrew 2012, Concomitant reactivity of the m-Terphenylindium dihydroxide [2,6-Mes2C6H3In(OH)2]4 toward carbon dioxide and ethylene glycol, Organometallics, vol. 31, no. 9, pp. 3802-3805.

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Title Concomitant reactivity of the m-Terphenylindium dihydroxide [2,6-Mes2C6H3In(OH)2]4 toward carbon dioxide and ethylene glycol
Formatted title Concomitant reactivity of the m-Terphenylindium dihydroxide [2,6-Mes2C6H3In(OH)2]toward carbon dioxide and ethylene glycol
Author(s) Ahmad, S. Usman
Beckmann, Jens
Duthie, Andrew
Journal name Organometallics
Volume number 31
Issue number 9
Start page 3802
End page 3805
Total pages 4
Publisher American Chemical Society
Place of publication Washington, D. C.
Publication date 2012-05-14
ISSN 0276-7333
1520-6041
Keyword(s) ethylene carbonate
stepwise reaction
Summary The stepwise reaction of [2,6-Mes2C6H3In(OH)2]4 with carbon dioxide and ethylene glycol proceeded with the formation of (2,6-Mes2C6H3In)4(CO3)2(OH)4(H2O)2 (1) and (2,6-Mes2C6H3In)4(OCH2CH2O)2(OH)4 (2), respectively, and eventually produced (2,6-Mes2C6H3In)4(CO3)2(OCH2CH2OH)2(OH)2 (3). Attempts to liberate ethylene carbonate upon heating of 3 were unsuccessful.
Language eng
Field of Research 039904 Organometallic Chemistry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2012, American Chemical Society
Persistent URL http://hdl.handle.net/10536/DRO/DU:30047045

Document type: Journal Article
Collection: School of Life and Environmental Sciences
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