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Synthesis and structure of an intramolecularly coordinated diaryltelluronic acid and its dimethyl ester

Beckmann, Jens, Bolsinger, Jens, Duthie, Andrew and Finke, Pamela 2012, Synthesis and structure of an intramolecularly coordinated diaryltelluronic acid and its dimethyl ester, Organometallics, vol. 31, no. 1, pp. 289-293.

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Title Synthesis and structure of an intramolecularly coordinated diaryltelluronic acid and its dimethyl ester
Author(s) Beckmann, Jens
Bolsinger, Jens
Duthie, Andrew
Finke, Pamela
Journal name Organometallics
Volume number 31
Issue number 1
Start page 289
End page 293
Total pages 5
Publisher American Chemical Society
Place of publication Washington, D.C.
Publication date 2012
ISSN 0276-7333
Keyword(s) derivatives
exchange
atoms
Summary The oxidation of the telluroxane cluster (8Me2NC10H6Te)6O8(OH)2 (4) or the diaryl ditelluride (8-Me2NC10H6Te)(2) (7) using H2O2 provided the diarylditelluronic acid [8-Me2NC10H6Te(O)(OH)2]2(O) (6), which is the second member of this compound class and the first one to contain an intramolecularly coordinated substituent. Attempts at recrystallizing 6 from Methanol provided the partial ester [8-Me2NC10H6Te(O)(OH)(OMe)]2(O) (8). In addition structural motifs of known diaryltelluronic acids were compared using DFT calculations.
Language eng
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
Copyright notice ©2011, American Chemical Society
Persistent URL http://hdl.handle.net/10536/DRO/DU:30047049

Document type: Journal Article
Collection: School of Life and Environmental Sciences
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Created: Mon, 13 Aug 2012, 13:10:15 EST