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Immobilization of large, aliovalent cations in the small-pore zeolite K-natrolite by means of pressure

Lee, Yongjae, Lee, Yongmoon, Seoung, Donghoon, Im, Jun-Hyuk, Hwang, Hee-Jung, Kim, Tae-Hyun, Liu, Dan, Liu, Zhenxian, Lee, Seung Yeop, Kao, Chi-Chang and Vogt, Thomas 2012, Immobilization of large, aliovalent cations in the small-pore zeolite K-natrolite by means of pressure, Angewandte chemie - international edition, vol. 51, no. 20, pp. 4848-4851, doi: 10.1002/anie.201201045.

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Title Immobilization of large, aliovalent cations in the small-pore zeolite K-natrolite by means of pressure
Author(s) Lee, Yongjae
Lee, Yongmoon
Seoung, Donghoon
Im, Jun-Hyuk
Hwang, Hee-Jung
Kim, Tae-Hyun
Liu, DanORCID iD for Liu, Dan orcid.org/0000-0001-6875-419X
Liu, Zhenxian
Lee, Seung Yeop
Kao, Chi-Chang
Vogt, Thomas
Journal name Angewandte chemie - international edition
Volume number 51
Issue number 20
Start page 4848
End page 4851
Total pages 4
Publisher Wiley - V C H Verlag GmbH & Co. KGaA
Place of publication Weinheim, Germany
Publication date 2012-05-14
ISSN 1433-7851
1521-3773
Keyword(s) high-pressure chemistry
ion exchange
lanthanides
X-ray diffraction
zeolites
Summary High-pressure ion exchange of small-pore zeolite K-natrolite allows immobilization of nominally non-exchangeable aliovalent cations such as trivalent europium. A sample exchanged at 3.0(1) GPa and 250 °C contains about 4.7 EuIII ions per unit cell, which is equivalent to over 90 % of the K+ cations being exchanged.
Language eng
DOI 10.1002/anie.201201045
Field of Research 040306 Mineralogy and Crystallography
020503 Nonlinear Optics and Spectroscopy
020406 Surfaces and Structural Properties of Condensed Matter
Socio Economic Objective 961103 Physical and Chemical Conditions of Water in Fresh, Ground and Surface Water Environments (excl. Urban and
HERDC Research category C1.1 Refereed article in a scholarly journal
Copyright notice ©2012, Wiley-VCH Verlag
Persistent URL http://hdl.handle.net/10536/DRO/DU:30047733

Document type: Journal Article
Collection: Institute for Frontier Materials
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