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Assessment of permethylated transition-metal sandwich complexes as internal reference redox systems in ionic liquids

Torriero, Angel A.J., Sunarso, Jaka, Forsyth, Maria and Pozo-Gonzalo, Cristina 2013, Assessment of permethylated transition-metal sandwich complexes as internal reference redox systems in ionic liquids, Physical chemistry chemical physics, vol. 15, no. 7, pp. 2547-2553.

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Title Assessment of permethylated transition-metal sandwich complexes as internal reference redox systems in ionic liquids
Author(s) Torriero, Angel A.J.
Sunarso, Jaka
Forsyth, Maria
Pozo-Gonzalo, Cristina
Journal name Physical chemistry chemical physics
Volume number 15
Issue number 7
Start page 2547
End page 2553
Total pages 7
Publisher Royal Society of Chemistry
Place of publication Cambridge, England
Publication date 2013
ISSN 1463-9076
1463-9084
Summary This work reports the voltammetric behaviour of decamethylcobaltocenium, DmCc+, in different ionic liquids for the first time. Its redox potential was studied relative to that of decamethylferrocene, DmFc, and it is shown that the difference in the mid-point potential between these two permethylated transition-metal sandwich complexes is independent of the ionic liquid composition. A variable difference in mid-point potential, in contrast, was observed for ferrocene and cobaltocenium relative to that of DmFc in similar ionic liquids. In addition, different limitations in the application of DmFc0/+ and DmCc+/0 couples as internal reference redox systems in ILs are discussed. From these, the observed spontaneous reaction between DmFc and oxygen leads to important implications toward the establishment of particular conditions for DmFc applications.
Language eng
Field of Research 109999 Technology not elsewhere classified
Socio Economic Objective 970110 Expanding Knowledge in Technology
HERDC Research category C1 Refereed article in a scholarly journal
Persistent URL http://hdl.handle.net/10536/DRO/DU:30055368

Document type: Journal Article
Collection: Institute for Frontier Materials
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Created: Tue, 27 Aug 2013, 12:07:52 EST