The synthesis of a dichloroalane complex and its reaction with an α-diimine

Alexander, Sean G., Cole, Marcus L., Hilder, Matthias, Morris, Jonathan C. and Patrick, Joanna B. 2008, The synthesis of a dichloroalane complex and its reaction with an α-diimine, Dalton transactions, vol. 2008, no. 45, pp. 6361-6363, doi: 10.1039/B814839B.

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Title The synthesis of a dichloroalane complex and its reaction with an α-diimine
Author(s) Alexander, Sean G.
Cole, Marcus L.
Hilder, Matthias
Morris, Jonathan C.
Patrick, Joanna B.
Journal name Dalton transactions
Volume number 2008
Issue number 45
Start page 6361
End page 6363
Total pages 3
Publisher Royal Society of Chemistry
Place of publication London, Eng.
Publication date 2008
ISSN 1364-5447
Keyword(s) dichloroalane complex
Summary Reaction of an α-diimine, {MesN[double bond, length as m-dash]CH}2 (Mes = 2,4,6-trimethylphenyl), with the dichloroalane [AlCl2H(IMes)] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords an N-heterocyclic carbene (NHC) transfer complex [AlCl2{MesNC([double bond, length as m-dash]IMes)C(H)NMes}] rather than the expected hydroalumination product.
Language eng
DOI 10.1039/B814839B
Field of Research 039999 Chemical Sciences not elsewhere classified
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C2.1 Other contribution to refereed journal
Copyright notice ©2008, Royal Society of Chemistry
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Document type: Journal Article
Collection: Institute for Frontier Materials
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