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Chemiluminescence detection with water-soluble iridium(III) complexes containing a sulfonate-functionalised ancillary ligand

Truong, Josephine, Spilstead, Kara B., Barbante, Gregory J., Doeven, Egan H., Wilson, David J.D., Barnett, Neil W., Henderson, Luke C., Altimari, Jarrad M., Hockey, Samantha C., Zhou, Ming and Francis, Paul S. 2014, Chemiluminescence detection with water-soluble iridium(III) complexes containing a sulfonate-functionalised ancillary ligand, Analyst, vol. 139, no. 22, pp. 6028-6035, doi: 10.1039/c4an01366b.

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Title Chemiluminescence detection with water-soluble iridium(III) complexes containing a sulfonate-functionalised ancillary ligand
Author(s) Truong, Josephine
Spilstead, Kara B.
Barbante, Gregory J.
Doeven, Egan H.ORCID iD for Doeven, Egan H. orcid.org/0000-0003-2677-4269
Wilson, David J.D.
Barnett, Neil W.
Henderson, Luke C.ORCID iD for Henderson, Luke C. orcid.org/0000-0002-4244-2056
Altimari, Jarrad M.
Hockey, Samantha C.
Zhou, Ming
Francis, Paul S.ORCID iD for Francis, Paul S. orcid.org/0000-0003-4165-6922
Journal name Analyst
Volume number 139
Issue number 22
Start page 6028
End page 6035
Total pages 8
Publisher Royal Society of Chemistry
Place of publication London, Eng.
Publication date 2014-11-21
ISSN 1364-5528
Keyword(s) Science & Technology
Physical Sciences
Chemistry, Analytical
Chemistry
ELECTROGENERATED CHEMILUMINESCENCE
SELECTIVE EXCITATION
ELECTROLUMINESCENT DEVICES
EMISSION COLOR
ELECTROCHEMILUMINESCENCE
BLUE
GREEN
PHOTOPHYSICS
DENSITY
DERIVATIVES
Summary The chemiluminescence from four cyclometalated iridium(III) complexes containing an ancillary bathophenanthroline-disulfonate ligand exhibited a wide range of emission colours (green to red), and in some cases intensities that are far greater than the commonly employed benchmark reagent, [Ru(bpy)3](2+). A similar complex incorporating a sulfonated triazolylpyridine-based ligand enabled the emission to be shifted into the blue region of the spectrum, but the responses with this complex were relatively poor. DFT calculations of electronic structure and emission spectra support the experimental findings.
Language eng
DOI 10.1039/c4an01366b
Field of Research 030101 Analytical Spectrometry
030103 Flow Analysis
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
Grant ID FT100100646
Copyright notice ©2014, Royal Society of Chemistry
Persistent URL http://hdl.handle.net/10536/DRO/DU:30069349

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