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Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate

Mallow,O, Bolsinger,J, Finke,P, Hesse,M, Chen,Y-S, Duthie,A, Grabowsky,S, Luger,P, Mebs,S and Beckmann,J 2014, Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate, Journal of the American Chemical Society, vol. 136, no. 31, pp. 10870-10873, doi: 10.1021/ja505648x.

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Title Oxygen transfer from an intramolecularly coordinated diaryltellurium oxide to acetonitrile. formation and combined AIM and ELI-D analysis of a novel diaryltellurium acetimidate
Author(s) Mallow,O
Bolsinger,J
Finke,P
Hesse,M
Chen,Y-S
Duthie,A
Grabowsky,S
Luger,P
Mebs,S
Beckmann,J
Journal name Journal of the American Chemical Society
Volume number 136
Issue number 31
Start page 10870
End page 10873
Total pages 4
Publisher American Chemical Society
Place of publication Washington, DC
Publication date 2014-07-15
ISSN 0002-7863
1520-5126
Summary The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC 10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC 10H6)2Te(OH)]Cl. © 2014 American Chemical Society.
Language eng
DOI 10.1021/ja505648x
Field of Research 039904 Organometallic Chemistry
Socio Economic Objective 970103 Expanding Knowledge in the Chemical Sciences
HERDC Research category C1 Refereed article in a scholarly journal
ERA Research output type C Journal article
Copyright notice ©2014, American Chemical Society
Persistent URL http://hdl.handle.net/10536/DRO/DU:30072708

Document type: Journal Article
Collection: School of Life and Environmental Sciences
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